[example: A Biased Coin]
Let $\Omega=\{H,T\}$, let $\mathcal F=\mathcal P(\Omega)$, and fix $p\in[0,1]$. Since $\mathcal F$ is the full power set, it contains $\Omega$, is closed under complements in $\Omega$, and is closed under countable unions of subsets of $\Omega$; hence $\mathcal F$ is a $\sigma$-algebra. Define
\begin{align*}
\mathbb P(\varnothing)=0,\quad \mathbb P(\{H\})=p,\quad \mathbb P(\{T\})=1-p,\quad \mathbb P(\Omega)=1.
\end{align*}
Equivalently, for every $A\subset\Omega$,
\begin{align*}
\mathbb P(A)=p\,\mathbf 1_{\{H\in A\}}+(1-p)\,\mathbf 1_{\{T\in A\}}.
\end{align*}
Indeed, for $A=\varnothing$ both indicators are $0$, so the formula gives $0$. For $A=\{H\}$ it gives $p\cdot1+(1-p)\cdot0=p$. For $A=\{T\}$ it gives $p\cdot0+(1-p)\cdot1=1-p$. For $A=\Omega$ it gives
\begin{align*}
p\cdot1+(1-p)\cdot1=p+1-p=1.
\end{align*}
Since $p\in[0,1]$, we have $0\le p\le1$. Subtracting $p\le1$ from $1$ gives $1-p\ge0$, and subtracting $0\le p$ from $1$ gives $1-p\le1$, so $1-p\in[0,1]$. Thus every assigned value lies in $[0,1]$, and
\begin{align*}
\mathbb P(\Omega)=1.
\end{align*}
It remains to verify countable additivity. Let $(A_n)_{n\in\mathbb N}$ be pairwise disjoint subsets of $\Omega$, and put
\begin{align*}
U=\bigcup_{n=1}^{\infty}A_n.
\end{align*}
For the outcome $H$, either $H\notin U$, in which case every term $\mathbf 1_{\{H\in A_n\}}$ is $0$, or $H\in U$, in which case $H\in A_m$ for exactly one index $m$ because the sets $A_n$ are pairwise disjoint. Therefore
\begin{align*}
\mathbf 1_{\{H\in U\}}=\sum_{n=1}^{\infty}\mathbf 1_{\{H\in A_n\}}.
\end{align*}
The same argument for $T$ gives
\begin{align*}
\mathbf 1_{\{T\in U\}}=\sum_{n=1}^{\infty}\mathbf 1_{\{T\in A_n\}}.
\end{align*}
Using the indicator formula for $\mathbb P$ on $U$,
\begin{align*}
\mathbb P(U)=p\,\mathbf 1_{\{H\in U\}}+(1-p)\,\mathbf 1_{\{T\in U\}}.
\end{align*}
Substituting the two indicator identities gives
\begin{align*}
\mathbb P(U)=p\sum_{n=1}^{\infty}\mathbf 1_{\{H\in A_n\}}+(1-p)\sum_{n=1}^{\infty}\mathbf 1_{\{T\in A_n\}}.
\end{align*}
Each of the two indicator sums has at most one nonzero term, so multiplying by the constants and adding term by term gives
\begin{align*}
\mathbb P(U)=\sum_{n=1}^{\infty}\left(p\,\mathbf 1_{\{H\in A_n\}}+(1-p)\,\mathbf 1_{\{T\in A_n\}}\right).
\end{align*}
For each $n$, the expression inside the parentheses is exactly $\mathbb P(A_n)$ by the indicator formula. Hence
\begin{align*}
\mathbb P\left(\bigcup_{n=1}^{\infty}A_n\right)=\sum_{n=1}^{\infty}\mathbb P(A_n).
\end{align*}
Thus $(\Omega,\mathcal F,\mathbb P)$ is a probability space, and the parameter $p$ is precisely the probability assigned to heads.
[/example]