[proofplan]
We show that conditional probability $\mathbb{P}(\cdot \mid B)$ is itself a probability measure on $(\Omega, \mathcal{F})$. Countable additivity of $\mathbb{P}(\cdot \mid B)$ then follows directly from countable additivity of $\mathbb{P}$.
[/proofplan]
[step:Express the conditional probability using the definition and distribute the intersection]
Let $(A_n)_{n \ge 1}$ be pairwise disjoint events. By definition of conditional probability,
\begin{align*}
\mathbb{P}\!\left(\bigcup_{n=1}^\infty A_n \;\Big|\; B\right) = \frac{\mathbb{P}\!\left(\left(\bigcup_{n=1}^\infty A_n\right) \cap B\right)}{\mathbb{P}(B)}.
\end{align*}
Distributing the intersection over the union,
\begin{align*}
\left(\bigcup_{n=1}^\infty A_n\right) \cap B = \bigcup_{n=1}^\infty (A_n \cap B).
\end{align*}
[/step]
[step:Verify disjointness of $A_n \cap B$ and apply countable additivity of $\mathbb{P}$]
Since the $A_n$ are pairwise disjoint, the sets $A_n \cap B$ are also pairwise disjoint: if $i \ne j$, then $(A_i \cap B) \cap (A_j \cap B) = (A_i \cap A_j) \cap B = \varnothing \cap B = \varnothing$. By [countable](/page/Countable%20Set) additivity of $\mathbb{P}$,
\begin{align*}
\mathbb{P}\!\left(\bigcup_{n=1}^\infty (A_n \cap B)\right) = \sum_{n=1}^\infty \mathbb{P}(A_n \cap B).
\end{align*}
[/step]
[step:Divide by $\mathbb{P}(B)$ to obtain the result]
Substituting back and dividing by $\mathbb{P}(B) > 0$:
\begin{align*}
\mathbb{P}\!\left(\bigcup_{n=1}^\infty A_n \;\Big|\; B\right) = \frac{\sum_{n=1}^\infty \mathbb{P}(A_n \cap B)}{\mathbb{P}(B)} = \sum_{n=1}^\infty \frac{\mathbb{P}(A_n \cap B)}{\mathbb{P}(B)} = \sum_{n=1}^\infty \mathbb{P}(A_n \mid B),
\end{align*}
where interchanging the sum and the division by the constant $\mathbb{P}(B)$ is valid because the sum has non-negative terms.
[/step]