Rewrite the coverage probability in terms of the MLE:
\begin{align*}
P_{\theta_0}(\theta_0 \in C_n) = P_{\theta_0}\!\left(|\hat{\theta}_n - \theta_0| \leq \frac{R_n}{\sqrt{n}}\right).
\end{align*}
Since $R_n \xrightarrow{a.s.} \Phi_0^{-1}(1-\alpha) > 0$, the ratio $\Phi_0^{-1}(1-\alpha)/R_n \xrightarrow{a.s.} 1$. Multiply both sides of the inequality inside the probability by $\Phi_0^{-1}(1-\alpha)/R_n$:
\begin{align*}
P_{\theta_0}(\theta_0 \in C_n) = P_{\theta_0}\!\left(\frac{\Phi_0^{-1}(1-\alpha)}{R_n} \cdot \sqrt{n}|\hat{\theta}_n - \theta_0| \leq \Phi_0^{-1}(1-\alpha)\right).
\end{align*}
By the asymptotic normality of the MLE, $\sqrt{n}(\hat{\theta}_n - \theta_0) \xrightarrow{d} N(0, I(\theta_0)^{-1})$. Since $\Phi_0^{-1}(1-\alpha)/R_n \xrightarrow{a.s.} 1$, Slutsky's lemma gives
\begin{align*}
\frac{\Phi_0^{-1}(1-\alpha)}{R_n} \cdot \sqrt{n}(\hat{\theta}_n - \theta_0) \xrightarrow{d} N(0, I(\theta_0)^{-1}).
\end{align*}
Therefore the coverage probability converges to
\begin{align*}
P\!\left(|Z_0| \leq \Phi_0^{-1}(1-\alpha)\right) = \Phi_0\!\left(\Phi_0^{-1}(1-\alpha)\right) = 1 - \alpha. \qquad \square
\end{align*}