[proofplan]
We first verify that the covariance entries are well-defined [real numbers](/page/Real%20Numbers) using the finite second moment hypothesis. Symmetry follows directly from commutativity of multiplication in $\mathbb{R}$. To prove positive semidefiniteness, we evaluate the quadratic form $a^\top \Sigma a$ and identify it with the expectation of the square of the centered scalar projection $a^\top(X-\mu)$.
[/proofplan]
[step:Verify that the covariance entries are finite]
For each $i \in \{1,\dots,p\}$, the hypothesis $\mathbb E[X_i^2] < \infty$ implies $\mathbb E[|X_i|] < \infty$, since $|t| \leq 1 + t^2$ for every $t \in \mathbb{R}$. Hence $\mu_i = \mathbb E[X_i]$ is a finite real number.
Fix $i,j \in \{1,\dots,p\}$. Define the centered coordinate random variables $Y_i: \Omega \to \mathbb{R}$ and $Y_j: \Omega \to \mathbb{R}$ by
\begin{align*}
Y_i(\omega) &:= X_i(\omega) - \mu_i, &
Y_j(\omega) &:= X_j(\omega) - \mu_j.
\end{align*}
Using $(u-v)^2 \leq 2u^2 + 2v^2$ for real numbers $u,v$, we have
\begin{align*}
\mathbb E[Y_i^2]
&= \int_\Omega (X_i(\omega)-\mu_i)^2\,d\mathbb P(\omega) \\
&\leq 2\int_\Omega X_i(\omega)^2\,d\mathbb P(\omega) + 2\mu_i^2 < \infty.
\end{align*}
The same argument gives $\mathbb E[Y_j^2] < \infty$. Finally, by $2|uv| \leq u^2+v^2$,
\begin{align*}
\mathbb E[|Y_iY_j|]
&= \int_\Omega |Y_i(\omega)Y_j(\omega)|\,d\mathbb P(\omega) \\
&\leq \frac{1}{2}\int_\Omega Y_i(\omega)^2\,d\mathbb P(\omega)
+ \frac{1}{2}\int_\Omega Y_j(\omega)^2\,d\mathbb P(\omega)
< \infty.
\end{align*}
Therefore $\Sigma_{ij} = \mathbb E[Y_iY_j]$ is well-defined and finite.
[/step]
[step:Use commutativity of multiplication to prove symmetry]
Let $i,j \in \{1,\dots,p\}$. With $Y_i = X_i-\mu_i$ and $Y_j = X_j-\mu_j$ as above, commutativity of multiplication in $\mathbb{R}$ gives $Y_iY_j = Y_jY_i$ pointwise on $\Omega$. Therefore
\begin{align*}
\Sigma_{ij}
&= \mathbb E[(X_i-\mu_i)(X_j-\mu_j)] \\
&= \mathbb E[(X_j-\mu_j)(X_i-\mu_i)] \\
&= \Sigma_{ji}.
\end{align*}
Thus $\Sigma^\top=\Sigma$.
[/step]
[step:Identify the quadratic form with the variance of a scalar projection]
Fix $a=(a_1,\dots,a_p) \in \mathbb{R}^p$. Define the centered scalar projection $Z_a: \Omega \to \mathbb{R}$ by
\begin{align*}
Z_a(\omega) := \sum_{i=1}^p a_i(X_i(\omega)-\mu_i).
\end{align*}
Since $Z_a$ is a finite linear combination of measurable real-valued random variables, it is measurable. Moreover, using the finite second moments of the centered coordinates, $Z_a^2$ is integrable. Indeed,
\begin{align*}
|Z_a(\omega)|^2
&= \left|\sum_{i=1}^p a_i(X_i(\omega)-\mu_i)\right|^2 \\
&\leq p\sum_{i=1}^p a_i^2(X_i(\omega)-\mu_i)^2,
\end{align*}
so
\begin{align*}
\mathbb E[Z_a^2]
\leq p\sum_{i=1}^p a_i^2\mathbb E[(X_i-\mu_i)^2] < \infty.
\end{align*}
By the definition of matrix multiplication and finite additivity of expectation over finite sums,
\begin{align*}
a^\top \Sigma a
&= \sum_{i=1}^p\sum_{j=1}^p a_i\Sigma_{ij}a_j \\
&= \sum_{i=1}^p\sum_{j=1}^p a_i a_j\mathbb E[(X_i-\mu_i)(X_j-\mu_j)] \\
&= \mathbb E\left[\sum_{i=1}^p\sum_{j=1}^p a_i a_j(X_i-\mu_i)(X_j-\mu_j)\right] \\
&= \mathbb E\left[\left(\sum_{i=1}^p a_i(X_i-\mu_i)\right)^2\right] \\
&= \mathbb E[Z_a^2].
\end{align*}
Since $Z_a^2 \geq 0$ pointwise on $\Omega$, its expectation is nonnegative:
\begin{align*}
a^\top \Sigma a = \mathbb E[Z_a^2] \geq 0.
\end{align*}
Because $a \in \mathbb{R}^p$ was arbitrary, $\Sigma$ is positive semidefinite.
[/step]