[proofplan]
We prove both distributional identities by characteristic functions. First we compute the characteristic function of the sample mean using the independence of $X_1,\dots,X_n$ and the characteristic function of a $\mathcal{N}_p(\mu,\Sigma)$ random vector. The resulting expression is exactly the characteristic function of $\mathcal{N}_p(\mu,\Sigma/n)$. Finally, applying the same characteristic-function computation to the affine transformation $\sqrt{n}(\bar{X}-\mu)$ gives the centred normal law with covariance matrix $\Sigma$.
[/proofplan]
[step:Declare the characteristic functions used in the proof]
For every random vector $Y : (\Omega,\mathcal{F}) \to (\mathbb{R}^p,\mathcal{B}(\mathbb{R}^p))$, define its characteristic function
\begin{align*}
\varphi_Y : \mathbb{R}^p &\to \mathbb{C} \\
t &\mapsto \mathbb{E}\left[\exp\left(i\,t^\top Y\right)\right].
\end{align*}
Since $X_i \sim \mathcal{N}_p(\mu,\Sigma)$ for each $i \in \{1,\dots,n\}$, the characteristic-function characterization of the multivariate normal distribution gives, for every $t \in \mathbb{R}^p$,
\begin{align*}
\varphi_{X_i}(t)
&=
\exp\left(i\,t^\top \mu-\frac{1}{2}t^\top \Sigma t\right).
\end{align*}
[/step]
[step:Compute the characteristic function of the sample mean]
Fix $t \in \mathbb{R}^p$. By the definition of $\bar{X}$ and linearity of the Euclidean inner product,
\begin{align*}
t^\top \bar{X}
&=
t^\top \left(\frac{1}{n}\sum_{i=1}^{n}X_i\right)
=
\sum_{i=1}^{n}\left(\frac{t}{n}\right)^\top X_i.
\end{align*}
Therefore
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\mathbb{E}\left[\exp\left(i\,t^\top \bar{X}\right)\right] \\
&=
\mathbb{E}\left[\exp\left(i\sum_{i=1}^{n}\left(\frac{t}{n}\right)^\top X_i\right)\right] \\
&=
\mathbb{E}\left[\prod_{i=1}^{n}\exp\left(i\left(\frac{t}{n}\right)^\top X_i\right)\right].
\end{align*}
The random variables
\begin{align*}
\omega \mapsto \exp\left(i\left(\frac{t}{n}\right)^\top X_i(\omega)\right)
\end{align*}
are independent because $X_1,\dots,X_n$ are independent and each displayed random variable is a Borel-measurable function of the corresponding $X_i$. Hence expectation factors over the product:
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\prod_{i=1}^{n}
\mathbb{E}\left[\exp\left(i\left(\frac{t}{n}\right)^\top X_i\right)\right] \\
&=
\prod_{i=1}^{n}
\varphi_{X_i}\left(\frac{t}{n}\right).
\end{align*}
Using the normal characteristic function from the previous step,
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\prod_{i=1}^{n}
\exp\left(i\left(\frac{t}{n}\right)^\top \mu
-\frac{1}{2}\left(\frac{t}{n}\right)^\top \Sigma \left(\frac{t}{n}\right)\right) \\
&=
\exp\left(n\left[
\frac{i}{n}t^\top \mu
-\frac{1}{2n^2}t^\top \Sigma t
\right]\right) \\
&=
\exp\left(i\,t^\top \mu-\frac{1}{2}t^\top \left(\frac{1}{n}\Sigma\right)t\right).
\end{align*}
This is the characteristic function of $\mathcal{N}_p(\mu,\Sigma/n)$. Therefore
\begin{align*}
\bar{X} \sim \mathcal{N}_p\left(\mu,\frac{1}{n}\Sigma\right).
\end{align*}
[guided]
Fix $t \in \mathbb{R}^p$. The characteristic function of $\bar{X}$ is determined by the scalar random variable $t^\top \bar{X}$. Since $\bar{X}$ is the average of the $X_i$, bilinearity of matrix multiplication gives
\begin{align*}
t^\top \bar{X}
&=
t^\top \left(\frac{1}{n}\sum_{i=1}^{n}X_i\right)
=
\sum_{i=1}^{n}\left(\frac{t}{n}\right)^\top X_i.
\end{align*}
Substituting this expression into the characteristic function gives
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\mathbb{E}\left[\exp\left(i\,t^\top \bar{X}\right)\right] \\
&=
\mathbb{E}\left[\exp\left(i\sum_{i=1}^{n}\left(\frac{t}{n}\right)^\top X_i\right)\right] \\
&=
\mathbb{E}\left[\prod_{i=1}^{n}\exp\left(i\left(\frac{t}{n}\right)^\top X_i\right)\right].
\end{align*}
The point of rewriting the exponential as a product is that independence can now be used. For each $i$, the map
\begin{align*}
\mathbb{R}^p &\to \mathbb{C} \\
x &\mapsto \exp\left(i\left(\frac{t}{n}\right)^\top x\right)
\end{align*}
is Borel-measurable, so the corresponding complex-valued random variables are independent because $X_1,\dots,X_n$ are independent. Their absolute values are all equal to $1$, so they are integrable. Thus the expectation of the product factors:
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\prod_{i=1}^{n}
\mathbb{E}\left[\exp\left(i\left(\frac{t}{n}\right)^\top X_i\right)\right] \\
&=
\prod_{i=1}^{n}
\varphi_{X_i}\left(\frac{t}{n}\right).
\end{align*}
Now use that each $X_i$ has distribution $\mathcal{N}_p(\mu,\Sigma)$. For every $i \in \{1,\dots,n\}$,
\begin{align*}
\varphi_{X_i}\left(\frac{t}{n}\right)
&=
\exp\left(i\left(\frac{t}{n}\right)^\top \mu
-\frac{1}{2}\left(\frac{t}{n}\right)^\top \Sigma \left(\frac{t}{n}\right)\right).
\end{align*}
Multiplying the $n$ identical factors gives
\begin{align*}
\varphi_{\bar{X}}(t)
&=
\prod_{i=1}^{n}
\exp\left(i\left(\frac{t}{n}\right)^\top \mu
-\frac{1}{2}\left(\frac{t}{n}\right)^\top \Sigma \left(\frac{t}{n}\right)\right) \\
&=
\exp\left(n\left[
\frac{i}{n}t^\top \mu
-\frac{1}{2n^2}t^\top \Sigma t
\right]\right) \\
&=
\exp\left(i\,t^\top \mu-\frac{1}{2}t^\top \left(\frac{1}{n}\Sigma\right)t\right).
\end{align*}
This final expression is exactly the characteristic function of a $\mathcal{N}_p(\mu,\Sigma/n)$ random vector. Therefore
\begin{align*}
\bar{X} \sim \mathcal{N}_p\left(\mu,\frac{1}{n}\Sigma\right).
\end{align*}
[/guided]
[/step]
[step:Center and rescale the sample mean]
Define the centred and rescaled random vector
\begin{align*}
Z : \Omega &\to \mathbb{R}^p \\
\omega &\mapsto \sqrt{n}\bigl(\bar{X}(\omega)-\mu\bigr).
\end{align*}
For every $t \in \mathbb{R}^p$,
\begin{align*}
\varphi_Z(t)
&=
\mathbb{E}\left[\exp\left(i\,t^\top \sqrt{n}(\bar{X}-\mu)\right)\right] \\
&=
\exp\left(-i\sqrt{n}\,t^\top\mu\right)
\mathbb{E}\left[\exp\left(i\,(\sqrt{n}t)^\top \bar{X}\right)\right] \\
&=
\exp\left(-i\sqrt{n}\,t^\top\mu\right)
\varphi_{\bar{X}}(\sqrt{n}t).
\end{align*}
Using the formula for $\varphi_{\bar{X}}$ proved above,
\begin{align*}
\varphi_Z(t)
&=
\exp\left(-i\sqrt{n}\,t^\top\mu\right)
\exp\left(i(\sqrt{n}t)^\top\mu
-\frac{1}{2}(\sqrt{n}t)^\top\left(\frac{1}{n}\Sigma\right)(\sqrt{n}t)\right) \\
&=
\exp\left(-\frac{1}{2}t^\top\Sigma t\right).
\end{align*}
This is the characteristic function of $\mathcal{N}_p(0,\Sigma)$. Hence
\begin{align*}
\sqrt{n}(\bar{X}-\mu) \sim \mathcal{N}_p(0,\Sigma).
\end{align*}
Together with the distribution of $\bar{X}$, this proves both asserted identities.
[/step]