[proofplan]
Represent the Wishart matrix as $W = X^\top X$ using its defining Gaussian sample matrix. The $j$th diagonal entry of $W$ is the sum of squares of the $j$th coordinates of the independent Gaussian rows. After normalizing those coordinates by $\sqrt{\sigma_{jj}}$, we obtain $n$ independent standard normal random variables, so the normalized diagonal entry is their sum of squares, which is precisely a chi-squared random variable with $n$ degrees of freedom.
[/proofplan]
[step:Extract the $j$th coordinate variables from the Gaussian sample matrix]
Fix $j \in \{1,\dots,p\}$ with $\sigma_{jj} > 0$. For each $i \in \{1,\dots,n\}$, define the real-valued random variable
\begin{align*}
Z_i: \Omega &\to \mathbb{R} \\
\omega &\mapsto \frac{X_{ij}(\omega)}{\sqrt{\sigma_{jj}}}.
\end{align*}
Since $X_i \sim \mathcal{N}_p(0,\Sigma)$, its $j$th coordinate $X_{ij}$ has one-dimensional Gaussian distribution $\mathcal{N}(0,\sigma_{jj})$. Because the rows $X_1,\dots,X_n$ are independent, the coordinate random variables $X_{1j},\dots,X_{nj}$ are independent. Therefore $Z_1,\dots,Z_n$ are independent random variables with distribution $\mathcal{N}(0,1)$.
[guided]
Fix an index $j \in \{1,\dots,p\}$ satisfying $\sigma_{jj} > 0$. The positivity assumption is needed so that division by $\sqrt{\sigma_{jj}}$ is defined. For each row index $i \in \{1,\dots,n\}$, define
\begin{align*}
Z_i: \Omega &\to \mathbb{R} \\
\omega &\mapsto \frac{X_{ij}(\omega)}{\sqrt{\sigma_{jj}}}.
\end{align*}
The row $X_i$ has distribution $\mathcal{N}_p(0,\Sigma)$. Hence its $j$th coordinate $X_{ij}$ is a real-valued Gaussian random variable with mean $0$ and variance equal to the $j$th diagonal covariance entry $\sigma_{jj}$. Thus
\begin{align*}
X_{ij} \sim \mathcal{N}(0,\sigma_{jj}).
\end{align*}
Scaling a centered Gaussian random variable by the reciprocal of its standard deviation gives a standard normal random variable, so
\begin{align*}
Z_i = \frac{X_{ij}}{\sqrt{\sigma_{jj}}} \sim \mathcal{N}(0,1).
\end{align*}
It remains to check independence. The random vectors $X_1,\dots,X_n$ are independent by the defining construction of the Wishart distribution. Each $X_{ij}$ is obtained from $X_i$ by applying the $j$th coordinate map, and independence is preserved under measurable transformations applied separately to independent random vectors. Therefore $X_{1j},\dots,X_{nj}$ are independent, and hence $Z_1,\dots,Z_n$ are independent standard normal random variables.
[/guided]
[/step]
[step:Identify the diagonal entry as a normalized sum of Gaussian squares]
By matrix multiplication,
\begin{align*}
w_{jj}
= (X^\top X)_{jj}
= \sum_{i=1}^n X_{ij}X_{ij}
= \sum_{i=1}^n X_{ij}^2.
\end{align*}
Dividing by $\sigma_{jj}$ and using the definition of $Z_i$ gives
\begin{align*}
\frac{w_{jj}}{\sigma_{jj}}
= \sum_{i=1}^n \frac{X_{ij}^2}{\sigma_{jj}}
= \sum_{i=1}^n Z_i^2.
\end{align*}
Since $Z_1,\dots,Z_n$ are independent standard normal random variables, the defining characterization of the chi-squared distribution with $n$ degrees of freedom gives
\begin{align*}
\sum_{i=1}^n Z_i^2 \sim \chi_n^2.
\end{align*}
Therefore
\begin{align*}
\frac{w_{jj}}{\sigma_{jj}} \sim \chi_n^2,
\end{align*}
as required.
[/step]