[proofplan]
Compare the joint law with the product law on measurable rectangles. Rectangles define independence and generate the product sigma-algebra.
[/proofplan]
[step:Independence implies product joint law]
Assume $X_1,\ldots,X_n$ are independent. For measurable rectangles $A_1\times\cdots\times A_n$ with $A_i\in\mathcal E_i$,
\begin{align*}
\mathcal L_X(A_1\times\cdots\times A_n)
&=\mathbb P(X_1\in A_1,\ldots,X_n\in A_n) \\
&=\prod_{i=1}^n\mathbb P(X_i\in A_i) \\
&=\prod_{i=1}^n\mu_i(A_i) \\
&=(\mu_1\otimes\cdots\otimes\mu_n)(A_1\times\cdots\times A_n).
\end{align*}
The measurable rectangles form a pi-system that generates the product sigma-algebra, so uniqueness of finite measures gives
\begin{align*}
\mathcal L_X=\mu_1\otimes\cdots\otimes\mu_n.
\end{align*}
[/step]
[step:Product joint law implies independence]
Conversely suppose $\mathcal L_X=\mu_1\otimes\cdots\otimes\mu_n$. For any $A_i\in\mathcal E_i$,
\begin{align*}
\mathbb P(X_1\in A_1,\ldots,X_n\in A_n)
&=\mathcal L_X(A_1\times\cdots\times A_n) \\
&=(\mu_1\otimes\cdots\otimes\mu_n)(A_1\times\cdots\times A_n) \\
&=\prod_{i=1}^n\mu_i(A_i) \\
&=\prod_{i=1}^n\mathbb P(X_i\in A_i).
\end{align*}
Thus the variables are independent.
[/step]