[proofplan]
Use the defining closure properties of a sigma-algebra: it contains the ambient set, is closed under complements, and is closed under countable unions.
[/proofplan]
[step:Verify the empty set and countable intersections]
Since $\Omega\in\mathcal F$ and $\mathcal F$ is closed under complements,
\begin{align*}
\varnothing=\Omega^c\in\mathcal F.
\end{align*}
If $A_n\in\mathcal F$ for all $n$, then $A_n^c\in\mathcal F$ for all $n$, and
\begin{align*}
\bigcap_{n=1}^{\infty}A_n=\left(\bigcup_{n=1}^{\infty}A_n^c\right)^c.
\end{align*}
The right-hand side belongs to $\mathcal F$, so $\bigcap_n A_n\in\mathcal F$.
[/step]
[step:Verify complements of unions and intersections]
Since each $A_n^c\in\mathcal F$ and sigma-algebras are closed under countable unions,
\begin{align*}
\bigcup_{n=1}^{\infty}A_n^c\in\mathcal F.
\end{align*}
Applying countable intersection closure to the sequence $(A_n^c)$ gives
\begin{align*}
\bigcap_{n=1}^{\infty}A_n^c\in\mathcal F.
\end{align*}
[/step]
[step:Verify set difference and symmetric difference]
If $A,B\in\mathcal F$, then
\begin{align*}
A\setminus B=A\cap B^c\in\mathcal F.
\end{align*}
Also
\begin{align*}
A\triangle B=(A\setminus B)\cup(B\setminus A),
\end{align*}
and both terms on the right are in $\mathcal F$. Hence $A\triangle B\in\mathcal F$.
[/step]