[proofplan]
The complement $A^c$ is measurable because $\mathcal F$ is a $\sigma$-algebra. The sets $A$ and $A^c$ are disjoint and their union is the whole sample space $\Omega$. Applying finite additivity of the probability measure to this disjoint union gives $\mathbb P(\Omega)=\mathbb P(A)+\mathbb P(A^c)$, and the normalization axiom $\mathbb P(\Omega)=1$ gives the desired identity.
[/proofplan]
[step:Verify that the complement is a measurable event]
Let $(\Omega,\mathcal F,\mathbb P)$ be the probability space from the statement, so $\Omega$ is the sample space, $\mathcal F$ is a $\sigma$-algebra on $\Omega$, and $\mathbb P:\mathcal F\to[0,1]$ is a probability measure. Let $A\in\mathcal F$ be the event from the statement, and define the complement of $A$ in $\Omega$ by $A^c:=\Omega\setminus A$. Since $\mathcal F$ is a $\sigma$-algebra and $A\in\mathcal F$, closure under complements in the [definition of a sigma-algebra](/page/Sigma-Algebra) gives $A^c\in\mathcal F$.
[/step]
[step:Decompose the sample space as a disjoint union]
Let $\varnothing$ denote the empty subset of $\Omega$. By the definition of complement,
\begin{align*}
A\cap A^c=\varnothing
\end{align*}
and
\begin{align*}
A\cup A^c=\Omega.
\end{align*}
Thus $A$ and $A^c$ are disjoint measurable subsets of $\Omega$ whose union is $\Omega$.
[/step]
[step:Apply finite additivity and probability normalization]
Because $A\in\mathcal F$, $A^c\in\mathcal F$, and $A\cap A^c=\varnothing$, finite additivity of the probability measure $\mathbb P$ gives
\begin{align*}
\mathbb P(A\cup A^c)=\mathbb P(A)+\mathbb P(A^c).
\end{align*}
Using $A\cup A^c=\Omega$ and the normalization axiom for a probability measure, $\mathbb P(\Omega)=1$, we obtain
\begin{align*}
1=\mathbb P(\Omega)=\mathbb P(A)+\mathbb P(A^c).
\end{align*}
Subtracting $\mathbb P(A)$ from both sides gives
\begin{align*}
\mathbb P(A^c)=1-\mathbb P(A).
\end{align*}
[guided]
We now use the two defining facts about a probability measure that are relevant here: additivity on disjoint measurable sets and normalization on the whole sample space. We have already verified that $A\in\mathcal F$ and $A^c\in\mathcal F$, and we have shown that
\begin{align*}
A\cap A^c=\varnothing.
\end{align*}
Therefore the hypotheses for finite additivity are satisfied: the two sets are measurable and disjoint. Applying finite additivity of the probability measure $\mathbb P$ to the pair of sets $A$ and $A^c$ gives
\begin{align*}
\mathbb P(A\cup A^c)=\mathbb P(A)+\mathbb P(A^c).
\end{align*}
The point of using the pair $A$ and $A^c$ is that their union is exactly the entire sample space:
\begin{align*}
A\cup A^c=\Omega.
\end{align*}
Substituting this identity into the left-hand side gives
\begin{align*}
\mathbb P(\Omega)=\mathbb P(A)+\mathbb P(A^c).
\end{align*}
Since $\mathbb P:\mathcal F\to[0,1]$ is a probability measure, its normalization axiom says that the whole sample space has probability one:
\begin{align*}
\mathbb P(\Omega)=1.
\end{align*}
Combining the last two displayed identities yields
\begin{align*}
1=\mathbb P(A)+\mathbb P(A^c).
\end{align*}
Finally, subtracting $\mathbb P(A)$ from both sides gives
\begin{align*}
\mathbb P(A^c)=1-\mathbb P(A).
\end{align*}
[/guided]
[/step]