[proofplan]
We first verify that the relation on equivalence classes does not depend on the chosen representatives. This uses only reflexivity and transitivity of Turing reducibility on subsets of $\mathbb{N}$. Once well-definedness is established, reflexivity and transitivity descend directly from the preorder $\le_T$, while antisymmetry follows because mutual reducibility of representatives is exactly membership in the same Turing degree.
[/proofplan]
[step:Check that the order relation is independent of representatives]
Let $A,A',B,B' \subseteq \mathbb{N}$ satisfy $A \equiv_T A'$ and $B \equiv_T B'$. Suppose $A \le_T B$. By the definition of $\equiv_T$, the assumptions give
\begin{align*}
A' \le_T A, \qquad A \le_T A', \qquad B' \le_T B, \qquad B \le_T B'.
\end{align*}
Using transitivity of $\le_T$ on subsets of $\mathbb{N}$, we obtain
\begin{align*}
A' \le_T A \le_T B \le_T B',
\end{align*}
and hence $A' \le_T B'$. Therefore the truth of $[A]_T \le [B]_T$ is independent of the chosen representatives $A$ and $B$, so $\le$ is well-defined on $\mathcal{D}_T$.
[guided]
We must show that the proposed definition
\begin{align*}
[A]_T \le [B]_T \iff A \le_T B
\end{align*}
does not change if we replace $A$ or $B$ by another set of the same Turing degree. Let $A,A',B,B' \subseteq \mathbb{N}$ be sets with $A \equiv_T A'$ and $B \equiv_T B'$, and assume $A \le_T B$.
The equivalence $A \equiv_T A'$ means both reductions hold:
\begin{align*}
A \le_T A' \quad \text{and} \quad A' \le_T A.
\end{align*}
Similarly, $B \equiv_T B'$ means
\begin{align*}
B \le_T B' \quad \text{and} \quad B' \le_T B.
\end{align*}
To prove that the new representatives also satisfy the desired comparison, we need $A' \le_T B'$. The available reductions compose in the order
\begin{align*}
A' \le_T A, \qquad A \le_T B, \qquad B \le_T B'.
\end{align*}
By transitivity of Turing reducibility on subsets of $\mathbb{N}$, these three reductions imply
\begin{align*}
A' \le_T B'.
\end{align*}
Thus replacing $A$ by an equivalent representative $A'$ and $B$ by an equivalent representative $B'$ preserves the truth of the comparison. Therefore $\le$ is a well-defined relation on the quotient set $\mathcal{D}_T$.
[/guided]
[/step]
[step:Prove reflexivity by choosing a representative]
Let $a \in \mathcal{D}_T$. Since $\mathcal{D}_T = \mathcal{P}(\mathbb{N})/{\equiv_T}$, there exists $A \subseteq \mathbb{N}$ such that $a = [A]_T$. Reflexivity of Turing reducibility gives $A \le_T A$. Hence, by the definition of $\le$ on $\mathcal{D}_T$,
\begin{align*}
a = [A]_T \le [A]_T = a.
\end{align*}
Thus $\le$ is reflexive.
[/step]
[step:Prove transitivity by composing representative reductions]
Let $a,b,c \in \mathcal{D}_T$ satisfy $a \le b$ and $b \le c$. Choose representatives $A,B,C \subseteq \mathbb{N}$ such that
\begin{align*}
a = [A]_T, \qquad b = [B]_T, \qquad c = [C]_T.
\end{align*}
By the definition of $\le$ on $\mathcal{D}_T$, the assumptions imply
\begin{align*}
A \le_T B \quad \text{and} \quad B \le_T C.
\end{align*}
Transitivity of $\le_T$ gives $A \le_T C$. Therefore
\begin{align*}
a = [A]_T \le [C]_T = c.
\end{align*}
So $\le$ is transitive.
[/step]
[step:Prove antisymmetry by identifying mutually reducible representatives]
Let $a,b \in \mathcal{D}_T$ satisfy $a \le b$ and $b \le a$. Choose representatives $A,B \subseteq \mathbb{N}$ such that
\begin{align*}
a = [A]_T, \qquad b = [B]_T.
\end{align*}
By the definition of $\le$ on $\mathcal{D}_T$, the assumptions give
\begin{align*}
A \le_T B \quad \text{and} \quad B \le_T A.
\end{align*}
By the definition of Turing equivalence, this is exactly $A \equiv_T B$. Hence $A$ and $B$ belong to the same $\equiv_T$-equivalence class, so
\begin{align*}
a = [A]_T = [B]_T = b.
\end{align*}
Thus $\le$ is antisymmetric.
[/step]
[step:Conclude that the Turing degrees are partially ordered]
The relation $\le$ on $\mathcal{D}_T$ is well-defined, reflexive, transitive, and antisymmetric by the preceding steps. Therefore $\le$ is a partial order on the set of Turing degrees $\mathcal{D}_T$.
[/step]