Stone's Theorem on One-Parameter Unitary Groups (Theorem # 6934)
Theorem
Let $H$ be a complex [Hilbert space](/page/Hilbert%20Space), and let $(U(t))_{t \in \mathbb{R}}$ be a strongly continuous one-parameter unitary group on $H$; that is, each $U(t):H \to H$ is unitary, $U(0)=I_H$, $U(t+s)=U(t)U(s)$ for all $s,t \in \mathbb{R}$, and for every $\psi \in H$ the map $t \mapsto U(t)\psi$ is continuous from $\mathbb{R}$ to $H$.
Then there exists a unique self-adjoint operator $\mathcal H:D(\mathcal H)\subset H \to H$ such that
\begin{align*}
U(t)=e^{-it\mathcal H}
\end{align*}
for every $t \in \mathbb{R}$, where the exponential is defined by the functional calculus for [self-adjoint operators](/page/Self-Adjoint%20Operators).
Moreover,
\begin{align*}
D(\mathcal H)=\left\{\psi \in H:\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}\text{ exists in }H\right\},
\end{align*}
and for every $\psi \in D(\mathcal H)$,
\begin{align*}
\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}=-i\mathcal H\psi.
\end{align*}
Knowledge Status
Discussion
Stone's Theorem on One-Parameter Unitary Groups records a quantum mechanics result: Let H be a complex 21, and let (U(t))t R be a strongly continuous one-parameter unitary group on H; that is, each U(t):H H is unitary, U(0)=IH, U(t+s)=U(t)U(s) for all s,t R,...
Proof
[proofplan]
We define the infinitesimal generator $A$ by differentiating the orbit $t \mapsto U(t)\psi$ at $t=0$. Smooth time-averages of orbit vectors give a dense supply of differentiable vectors, so $A$ is densely defined. Laplace-transform resolvent formulas show that $\lambda I_H-A$ is onto for every real $\lambda \neq 0$, which upgrades skew-symmetry to skew-adjointness. Then $\mathcal H:=iA$ is self-adjoint, and the [spectral theorem for self-adjoint operators](/theorems/6911) identifies the original group with $e^{-it\mathcal H}$.
[/proofplan]
[step:Define the infinitesimal generator on differentiable orbit vectors]
Define the domain
\begin{align*}
D(A):=\left\{\psi \in H:\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}\text{ exists in }H\right\}.
\end{align*}
Define the operator $A:D(A)\to H$ by
\begin{align*}
A\psi:=\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}.
\end{align*}
For $\psi \in D(A)$ and $s \in \mathbb{R}$, the group law gives
\begin{align*}
\frac{U(t)U(s)\psi-U(s)\psi}{t}
=
U(s)\frac{U(t)\psi-\psi}{t}.
\end{align*}
Since $U(s):H \to H$ is bounded and linear, taking $t \to 0$ gives $U(s)\psi \in D(A)$ and
\begin{align*}
A U(s)\psi=U(s)A\psi.
\end{align*}
Thus $D(A)$ is invariant under every $U(s)$, and $A$ commutes with the group on its domain.
[/step]
[step:Construct a dense subspace of differentiable vectors by time averaging]
Let $\mathcal{L}^1$ denote one-dimensional [Lebesgue measure](/page/Lebesgue%20Measure) on $\mathbb{R}$. Let $\varphi \in C_c^\infty(\mathbb{R})$ and $\psi \in H$. Define the averaged vector
\begin{align*}
\psi_\varphi:=\int_{\mathbb{R}}\varphi(t)U(t)\psi\,d\mathcal{L}^1(t),
\end{align*}
where the integral is the Bochner integral in $H$. The map $t \mapsto \varphi(t)U(t)\psi$ is continuous with compact support, hence Bochner integrable.
For $h \neq 0$, using the group law and the substitution $r=t+h$, which preserves one-dimensional Lebesgue measure $d\mathcal{L}^1(r)=d\mathcal{L}^1(t)$, we obtain
\begin{align*}
\frac{U(h)\psi_\varphi-\psi_\varphi}{h}
=
\int_{\mathbb{R}}\frac{\varphi(t-h)-\varphi(t)}{h}U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
Since $\varphi \in C_c^\infty(\mathbb{R})$, the difference quotients converge uniformly to $-\varphi'$ and are supported in a fixed compact set for all sufficiently small $h$. Therefore the norm convergence of the Bochner integrals follows from [uniform convergence](/page/Uniform%20Convergence) of the scalar coefficient and boundedness of $\|U(t)\psi\|_H=\|\psi\|_H$. Hence $\psi_\varphi \in D(A)$ and
\begin{align*}
A\psi_\varphi
=
-\int_{\mathbb{R}}\varphi'(t)U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
[guided]
The point of the averaging construction is to manufacture differentiability in the group parameter. A general orbit $t \mapsto U(t)\psi$ is only assumed continuous, so differentiating it directly may fail. But after averaging against a smooth compactly supported scalar function, the differentiability can be transferred onto that scalar function.
Let $\varphi \in C_c^\infty(\mathbb{R})$ and $\psi \in H$, and define
\begin{align*}
\psi_\varphi:=\int_{\mathbb{R}}\varphi(t)U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
This Bochner integral is well-defined because $t \mapsto U(t)\psi$ is continuous, $\varphi$ is continuous with compact support, and $\|U(t)\psi\|_H=\|\psi\|_H$ for every $t \in \mathbb{R}$.
We now compute the difference quotient. For $h \neq 0$,
\begin{align*}
U(h)\psi_\varphi
=
\int_{\mathbb{R}}\varphi(t)U(h+t)\psi\,d\mathcal{L}^1(t).
\end{align*}
Apply the substitution $r=t+h$. The transformation $t \mapsto r=t+h$ preserves one-dimensional Lebesgue measure, so $d\mathcal{L}^1(r)=d\mathcal{L}^1(t)$, and the integration domain remains all of $\mathbb{R}$. Thus
\begin{align*}
U(h)\psi_\varphi
=
\int_{\mathbb{R}}\varphi(r-h)U(r)\psi\,d\mathcal{L}^1(r).
\end{align*}
Renaming $r$ as $t$ gives
\begin{align*}
\frac{U(h)\psi_\varphi-\psi_\varphi}{h}
=
\int_{\mathbb{R}}\frac{\varphi(t-h)-\varphi(t)}{h}U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
Because $\varphi$ is smooth with compact support, the scalar difference quotients
\begin{align*}
t \mapsto \frac{\varphi(t-h)-\varphi(t)}{h}
\end{align*}
converge uniformly to $-\varphi'(t)$ as $h \to 0$, and for $|h|$ sufficiently small their supports lie inside one fixed compact subset of $\mathbb{R}$. Since $\|U(t)\psi\|_H=\|\psi\|_H$, the norm of the error is bounded by the uniform scalar error times $\|\psi\|_H$ times the finite Lebesgue measure of that compact set. Therefore the Bochner integrals converge in $H$, and
\begin{align*}
A\psi_\varphi
=
-\int_{\mathbb{R}}\varphi'(t)U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
So every such averaged vector is in $D(A)$.
It remains to explain why these differentiable averaged vectors are dense. Choose $\eta \in C_c^\infty(\mathbb{R})$ with $\eta \geq 0$ and
\begin{align*}
\int_{\mathbb{R}}\eta(t)\,d\mathcal{L}^1(t)=1.
\end{align*}
For $\varepsilon>0$, define the rescaled smooth function $\eta_\varepsilon:\mathbb{R}\to\mathbb{R}$ by
\begin{align*}
\eta_\varepsilon(t):=\varepsilon^{-1}\eta(t/\varepsilon).
\end{align*}
Then $\eta_\varepsilon$ is supported in a shrinking neighbourhood of $0$ as $\varepsilon \downarrow 0$, and
\begin{align*}
\psi_{\eta_\varepsilon}-\psi=
\int_{\mathbb{R}}\eta_\varepsilon(t)(U(t)\psi-\psi)\,d\mathcal{L}^1(t).
\end{align*}
To prove convergence in $H$, fix $\delta>0$. Strong continuity at $0$ gives $\rho>0$ such that $\|U(t)\psi-\psi\|_H<\delta$ whenever $|t|<\rho$. For all sufficiently small $\varepsilon$, the support of $\eta_\varepsilon$ lies in $(-\rho,\rho)$, and therefore
\begin{align*}
\|\psi_{\eta_\varepsilon}-\psi\|_H\leq
\int_{\mathbb{R}}\eta_\varepsilon(t)\|U(t)\psi-\psi\|_H\,d\mathcal{L}^1(t)
\leq \delta\int_{\mathbb{R}}\eta_\varepsilon(t)\,d\mathcal{L}^1(t)=\delta.
\end{align*}
Since $\delta>0$ was arbitrary, $\psi_{\eta_\varepsilon}\to\psi$ in $H$. Each $\psi_{\eta_\varepsilon}$ belongs to $D(A)$ by the differentiability computation above, so $D(A)$ is dense in $H$.
[/guided]
It remains to see that these vectors are dense. Choose $\eta \in C_c^\infty(\mathbb{R})$ with $\eta \geq 0$ and
\begin{align*}
\int_{\mathbb{R}}\eta(t)\,d\mathcal{L}^1(t)=1.
\end{align*}
For $\varepsilon>0$, define $\eta_\varepsilon:\mathbb{R}\to\mathbb{R}$ by
\begin{align*}
\eta_\varepsilon(t):=\varepsilon^{-1}\eta(t/\varepsilon).
\end{align*}
Then
\begin{align*}
\psi_{\eta_\varepsilon}-\psi
=
\int_{\mathbb{R}}\eta_\varepsilon(t)(U(t)\psi-\psi)\,d\mathcal{L}^1(t).
\end{align*}
The strong continuity of $U$ at $0$ implies that this norm tends to $0$ as $\varepsilon \downarrow 0$. Hence $D(A)$ is dense in $H$.
[/step]
[step:Prove that the generator is skew-symmetric]
Throughout the proof, the [Hilbert space](/page/Hilbert%20Space) [inner product](/page/Inner%20Product) $(\cdot,\cdot)_H$ is linear in the first variable and conjugate-linear in the second variable.
Let $\psi,\phi \in D(A)$. Since each $U(t)$ is unitary,
\begin{align*}
(U(t)\psi,U(t)\phi)_H=(\psi,\phi)_H
\end{align*}
for every $t \in \mathbb{R}$. Hence
\begin{align*}
\left(\frac{U(t)\psi-\psi}{t},U(t)\phi\right)_H
+
\left(\psi,\frac{U(t)\phi-\phi}{t}\right)_H
=
0.
\end{align*}
Taking $t \to 0$, using strong continuity of $U(t)\phi \to \phi$ and the defining limits for $A\psi$ and $A\phi$, gives
\begin{align*}
(A\psi,\phi)_H+(\psi,A\phi)_H=0.
\end{align*}
Thus $A$ is skew-symmetric on the dense domain $D(A)$.
[/step]
[step:Identify the real resolvents by Laplace transform formulas]
Let $\mathcal{L}(H)$ denote the [Banach space](/page/Banach%20Space) of bounded linear operators from $H$ to $H$. Let $\lambda>0$. Define the [bounded linear operator](/page/Bounded%20Linear%20Operator) $R_\lambda \in \mathcal{L}(H)$ by
\begin{align*}
R_\lambda\psi:=\int_0^\infty e^{-\lambda t}U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
The integral is Bochner integrable because
\begin{align*}
\int_0^\infty e^{-\lambda t}\|U(t)\psi\|_H\,d\mathcal{L}^1(t)
=
\|\psi\|_H\int_0^\infty e^{-\lambda t}\,d\mathcal{L}^1(t)
=
\frac{1}{\lambda}\|\psi\|_H.
\end{align*}
Thus $\|R_\lambda\|_{\mathcal{L}(H)}\leq \lambda^{-1}$.
We will repeatedly use the following endpoint-average estimate for Bochner integrals. If $g:[0,a]\to H$ is continuous at $0$, then
\begin{align*}
\left\|\frac{1}{h}\int_0^h g(r)\,d\mathcal{L}^1(r)-g(0)\right\|_H
\leq
\sup_{0\leq r\leq h}\|g(r)-g(0)\|_H
\end{align*}
for $0<h\leq a$, and the right-hand side tends to $0$ as $h\downarrow 0$. The identical estimate on $[-a,0]$ follows by replacing $[0,h]$ with $[-h,0]$. We also use that if $g:\mathbb{R}\to H$ is Bochner integrable, then the absolute continuity of the Bochner integral gives $\int_E g\,d\mathcal{L}^1\to 0$ in $H$ whenever $\mathcal{L}^1(E)\to 0$ along measurable sets contained in a fixed finite-measure region.
For $h>0$, the group law and the substitution $r=t+h$, which preserves $\mathcal{L}^1$, give
\begin{align*}
\frac{U(h)R_\lambda\psi-R_\lambda\psi}{h}
=
\frac{e^{\lambda h}-1}{h}\int_h^\infty e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r)
-
\frac{1}{h}\int_0^h e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r).
\end{align*}
As $h \downarrow 0$, the first term converges to $\lambda R_\lambda\psi$: the scalar factor converges to $\lambda$, and the missing interval contribution $\int_0^h e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r)$ has norm at most $h\|\psi\|_H$. The second term converges to $\psi$ by the continuity of averages at the endpoint. Indeed,
\begin{align*}
\left\|\frac{1}{h}\int_0^h e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r)-\psi\right\|_H
\leq
\sup_{0\leq r\leq h}\|e^{-\lambda r}U(r)\psi-\psi\|_H.
\end{align*}
The right-hand side tends to $0$ as $h\downarrow 0$ because $r\mapsto e^{-\lambda r}U(r)\psi$ is continuous at $0$.
For negative increments, let $k=-h>0$. Using the substitution $r=t-k$, which again preserves $\mathcal{L}^1$, we obtain
\begin{align*}
\frac{U(-k)R_\lambda\psi-R_\lambda\psi}{-k}
=
\frac{1-e^{-\lambda k}}{k}R_\lambda\psi
-
\frac{e^{-\lambda k}}{k}\int_{-k}^0 e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r).
\end{align*}
As $k \downarrow 0$, the first term converges to $\lambda R_\lambda\psi$. The second term converges to $\psi$ by the same endpoint-average argument: the map $r\mapsto e^{-\lambda r}U(r)\psi$ is continuous at $0$, and therefore
\begin{align*}
\left\|\frac{1}{k}\int_{-k}^0 e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r)-\psi\right\|_H
\leq
\sup_{-k\leq r\leq 0}\|e^{-\lambda r}U(r)\psi-\psi\|_H
\end{align*}
tends to $0$. Therefore the two-sided limit exists, so $R_\lambda\psi \in D(A)$ and
\begin{align*}
A R_\lambda\psi=\lambda R_\lambda\psi-\psi.
\end{align*}
Therefore
\begin{align*}
(\lambda I_H-A)R_\lambda\psi=\psi.
\end{align*}
So $\lambda I_H-A$ is surjective.
For $\lambda<0$, define
\begin{align*}
R_\lambda\psi:=-\int_{-\infty}^0 e^{-\lambda t}U(t)\psi\,d\mathcal{L}^1(t).
\end{align*}
The integral is Bochner integrable because $\lambda<0$ makes $e^{-\lambda t}$ integrable on $(-\infty,0]$ and $\|U(t)\psi\|_H=\|\psi\|_H$.
For $h>0$, using the substitution $r=t+h$, which preserves one-dimensional Lebesgue measure and changes the interval $(-\infty,0]$ into $(-\infty,h]$, we obtain
\begin{align*}
\frac{U(h)R_\lambda\psi-R_\lambda\psi}{h}
=
\frac{e^{\lambda h}-1}{h}R_\lambda\psi
-
\frac{e^{\lambda h}}{h}\int_0^h e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r).
\end{align*}
As $h\downarrow 0$, the first term converges to $\lambda R_\lambda\psi$, and the second term converges to $\psi$ by the endpoint-average argument applied to the continuous map $r\mapsto e^{-\lambda r}U(r)\psi$ at $0$.
For negative increments, let $k=-h>0$. Using the substitution $r=t-k$, which preserves one-dimensional Lebesgue measure and changes $(-\infty,0]$ into $(-\infty,-k]$, we get
\begin{align*}
\frac{U(-k)R_\lambda\psi-R_\lambda\psi}{-k}
=
\frac{e^{-\lambda k}-1}{k}\int_{-\infty}^{-k} e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r)
-
\frac{1}{k}\int_{-k}^0 e^{-\lambda r}U(r)\psi\,d\mathcal{L}^1(r).
\end{align*}
The first term converges to $\lambda R_\lambda\psi$, because the truncated integral converges in $H$ to $-R_\lambda\psi$ and the scalar factor converges to $-\lambda$. The second term converges to $\psi$ by the same endpoint-average argument. Hence $R_\lambda\psi\in D(A)$ and
\begin{align*}
A R_\lambda\psi=\lambda R_\lambda\psi-\psi.
\end{align*}
Therefore
\begin{align*}
(\lambda I_H-A)R_\lambda\psi=\psi.
\end{align*}
Thus $\lambda I_H-A$ is surjective for every real $\lambda \neq 0$.
[/step]
[step:Show that the skew-symmetric generator is skew-adjoint]
We prove that $A^*=-A$. Since $A$ is densely defined and skew-symmetric, we have $A \subset -A^*$.
Let $\eta \in D(A^*)$. We show $\eta \in D(A)$ and $A^*\eta=-A\eta$. Fix $\lambda>0$. Since $\lambda I_H+A$ is surjective by the already proved surjectivity of $\mu I_H-A$ with $\mu=-\lambda$, choose $\xi \in D(A)$ such that
\begin{align*}
(\lambda I_H+A)\xi=(\lambda I_H-A^*)\eta.
\end{align*}
For every $\phi \in D(A)$, the definition of the adjoint gives
\begin{align*}
((\lambda I_H-A)\phi,\eta-\xi)_H
=
(\phi,(\lambda I_H-A^*)\eta)_H-(\phi,(\lambda I_H-A^*)\xi)_H.
\end{align*}
Because $\xi\in D(A)$ and $A\subset -A^*$, we have $A^*\xi=-A\xi$, so
\begin{align*}
(\lambda I_H-A^*)\xi=(\lambda I_H+A)\xi.
\end{align*}
The defining choice of $\xi$ therefore gives
\begin{align*}
((\lambda I_H-A)\phi,\eta-\xi)_H=0
\end{align*}
for every $\phi\in D(A)$. Because $\lambda I_H-A$ is surjective, its range is all of $H$, so $\eta-\xi=0$. Hence $\eta=\xi \in D(A)$. Substituting $\eta=\xi$ into
\begin{align*}
(\lambda I_H+A)\xi=(\lambda I_H-A^*)\eta
\end{align*}
gives $A\eta=-A^*\eta$, or equivalently
\begin{align*}
A^*\eta=-A\eta.
\end{align*}
Thus $D(A^*)\subset D(A)$ and $A^*=-A$. Therefore $A$ is skew-adjoint.
[/step]
[step:Convert the skew-adjoint generator into a self-adjoint operator]
Define the operator $\mathcal H:D(A)\to H$ by
\begin{align*}
\mathcal H\psi:=iA\psi.
\end{align*}
Since $A^*=-A$, we have
\begin{align*}
\mathcal H^*=(iA)^*=-iA^*=-i(-A)=iA=\mathcal H.
\end{align*}
Thus $\mathcal H$ is self-adjoint, with $D(\mathcal H)=D(A)$. By the definition of $A$,
\begin{align*}
\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}=A\psi=-i\mathcal H\psi
\end{align*}
for every $\psi \in D(\mathcal H)$.
[/step]
[step:Recover the original unitary group from the self-adjoint generator]
By the [Spectral Theorem for Normal Operators](/theorems/2695), applied in its self-adjoint projection-valued-measure form to the [self-adjoint operator](/page/Self-Adjoint%20Operators) $\mathcal H$, there is a projection-valued measure $E$ on the Borel subsets of $\mathbb{R}$ such that
\begin{align*}
\mathcal H=\int_{\mathbb{R}}\lambda\,dE(\lambda),
\end{align*}
and the functional calculus for self-adjoint operators defines a strongly continuous unitary group $(V(t))_{t \in \mathbb{R}}$ by
\begin{align*}
V(t):=e^{-it\mathcal H}
=
\int_{\mathbb{R}}e^{-it\lambda}\,dE(\lambda).
\end{align*}
For $\psi \in D(\mathcal H)$, the functional calculus gives $V(t)\psi \in D(\mathcal H)$ for every $t \in \mathbb{R}$, because multiplication by $e^{-it\lambda}$ preserves the integrability condition defining $D(\mathcal H)$. It also gives
\begin{align*}
\lim_{t \to 0}\frac{V(t)\psi-\psi}{t}=-i\mathcal H\psi=A\psi.
\end{align*}
Indeed, for each $\psi\in H$, define the finite positive Borel measure $\mu_\psi$ on $\mathbb{R}$ by $\mu_\psi(B):=(E(B)\psi,\psi)_H$ for every Borel set $B\subset\mathbb{R}$. In the spectral representation, the difference quotient is the scalar multiplier
\begin{align*}
\lambda \mapsto \frac{e^{-it\lambda}-1}{t},
\end{align*}
which converges pointwise to $-i\lambda$. If $\psi\in D(\mathcal H)$, then $\int_{\mathbb{R}}\lambda^2\,d\mu_\psi(\lambda)<\infty$, and the elementary bound
\begin{align*}
\left|\frac{e^{-it\lambda}-1}{t}\right|\leq |\lambda|
\end{align*}
gives convergence in $L^2(\mathbb{R},\mu_\psi)$ by the [Dominated Convergence Theorem](/theorems/4), applied to the squared absolute values and dominated by $\lambda^2$. Thus $U(t)$ and $V(t)$ are strongly continuous unitary groups with the same generator $A$.
To prove equality, fix $\psi \in D(A)$ and $t \in \mathbb{R}$. Define the map $F:[0,t]\to H$ by
\begin{align*}
F(s):=V(t-s)U(s)\psi
\end{align*}
if $t\geq 0$; for $t<0$ the same argument is applied on the interval $[t,0]$. Since $D(A)=D(\mathcal H)$ is invariant under both groups, $A$ commutes with $U(s)$ on $D(A)$, and the functional calculus gives $AV(r)\zeta=V(r)A\zeta$ for every $\zeta \in D(A)$ and $r \in \mathbb{R}$.
We now verify the differentiability used in the product rule. For $\zeta\in D(A)$ and $s\in\mathbb{R}$,
\begin{align*}
\lim_{h\to 0}\frac{U(s+h)\zeta-U(s)\zeta}{h}=U(s)A\zeta=A U(s)\zeta.
\end{align*}
The same computation for $V$ gives the derivative $\frac{d}{dr}V(r)\zeta=A V(r)\zeta$ on $D(A)$. Therefore $F$ is differentiable by the product rule for strongly differentiable Hilbert-space-valued maps and
\begin{align*}
F'(s)=V(t-s)A U(s)\psi - V(t-s)A U(s)\psi=0.
\end{align*}
Hence $F$ is constant. Evaluating at $s=0$ and $s=t$ gives
\begin{align*}
V(t)\psi=U(t)\psi.
\end{align*}
Since $D(A)$ is dense in $H$ and $U(t),V(t):H\to H$ are bounded linear operators, equality extends to all $\psi \in H$. Therefore
\begin{align*}
U(t)=e^{-it\mathcal H}
\end{align*}
for every $t \in \mathbb{R}$.
[/step]
[step:Prove uniqueness of the self-adjoint generator]
Suppose $\mathcal K:D(\mathcal K)\subset H\to H$ is another self-adjoint operator satisfying
\begin{align*}
U(t)=e^{-it\mathcal K}
\end{align*}
for every $t \in \mathbb{R}$. By the functional calculus for self-adjoint operators, for every $\psi \in D(\mathcal K)$,
\begin{align*}
\lim_{t \to 0}\frac{U(t)\psi-\psi}{t}
=
\lim_{t \to 0}\frac{e^{-it\mathcal K}\psi-\psi}{t}
=
-i\mathcal K\psi.
\end{align*}
Hence $D(\mathcal K)\subset D(A)$ and $A\psi=-i\mathcal K\psi$ on $D(\mathcal K)$, so $\mathcal K\subset iA=\mathcal H$.
Both $\mathcal K$ and $\mathcal H$ are self-adjoint. A self-adjoint operator has no proper self-adjoint extension, because equality with its adjoint fixes both the action and the domain. Therefore $\mathcal K=\mathcal H$.
This proves existence, the stated domain characterization, the derivative identity, and uniqueness.
[/step]
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