For every $\alpha\in\mathbb C$, the series
\begin{align*}
\psi_\alpha=e^{-|\alpha|^2/2}\sum_{n=0}^{\infty}\frac{\alpha^n}{\sqrt{n!}}\psi_n,
\end{align*}
converges in $L^2(\mathbb R)$ and defines the unique normalised vector in $\mathcal D(a)$ satisfying
\begin{align*}
a\psi_\alpha=\alpha\psi_\alpha,\qquad (\psi_0,\psi_\alpha)_{L^2}>0.
\end{align*}