[proofplan]
We construct the example inside the free unital algebra on three noncommuting generators. First we define a reference unital linear functional that extracts the constant term, so the one-generator subalgebras are freely independent in the usual alternating-word sense. Then we modify the functional only on words involving all three generators, forcing the mixed moment $\varphi(x_1x_2x_3)$ to be nonzero while leaving every two-generator subalgebra unchanged. This preserves pairwise freeness but violates the defining centered alternating-word condition for joint freeness.
[/proofplan]
[step:Build the ambient algebra and define the modified functional]
Let $A := \mathbb{C}\langle x_1,x_2,x_3\rangle$ be the free unital associative $\mathbb{C}$-algebra on generators $x_1,x_2,x_3$. Its standard vector-space basis consists of the empty word $1$ and all nonempty words in the alphabet $\{x_1,x_2,x_3\}$.
Define the unital linear functional \begin{align*}\psi: A \to \mathbb{C}\end{align*} by setting $\psi(1)=1$ and $\psi(w)=0$ for every nonempty basis word $w$.
Now define another unital linear functional \begin{align*}\varphi: A \to \mathbb{C}\end{align*} on the same basis as follows. Set $\varphi(1)=1$. If $w$ is a nonempty word involving at most two of the symbols $x_1,x_2,x_3$, set $\varphi(w):=\psi(w)=0$. Set
\begin{align*}
\varphi(x_1x_2x_3)=1.
\end{align*}
For every remaining basis word, namely every basis word involving all three symbols and different from $x_1x_2x_3$, set $\varphi(w):=0$. Extending by linearity gives a well-defined unital linear functional on $A$, so $(A,\varphi)$ is an algebraic noncommutative probability space.
[guided]
The free algebra $A=\mathbb{C}\langle x_1,x_2,x_3\rangle$ is useful because its elements have unique expansions as finite linear combinations of words in the generators. This means we can define a linear functional by prescribing its value on each basis word.
We first define
\begin{align*}
\psi: A \to \mathbb{C}
\end{align*}
by $\psi(1)=1$ and $\psi(w)=0$ for every nonempty word $w$. Thus $\psi$ is the constant-term functional: it returns the coefficient of the empty word.
The modified functional
\begin{align*}
\varphi: A \to \mathbb{C}
\end{align*}
is designed to agree with $\psi$ on every word that uses at most two generators, but to disagree on one genuinely three-generator word. More precisely, $\varphi(1)=1$, $\varphi(w)=0$ for every nonempty word using at most two of the symbols $x_1,x_2,x_3$, and
\begin{align*}
\varphi(x_1x_2x_3)=1.
\end{align*}
All other basis words involving all three generators are assigned value $0$.
Because every element of $A$ is a finite linear combination of basis words, these assignments determine exactly one linear functional $\varphi:A\to\mathbb{C}$. Since $\varphi(1)=1$, this functional is unital. No positivity condition is required in the algebraic definition of a noncommutative probability space used here.
[/guided]
[/step]
[step:Choose the three one-generator subalgebras]
For each $i \in \{1,2,3\}$, define
\begin{align*}
A_i := \mathbb{C}\langle x_i\rangle \subset A.
\end{align*}
Thus $A_i$ is the unital subalgebra of $A$ generated by $x_i$. Equivalently, every element of $A_i$ has the form
\begin{align*}
a = c_0 1 + \sum_{m=1}^{N} c_m x_i^m
\end{align*}
for some $N \in \mathbb{N}$ and coefficients $c_0,c_1,\dots,c_N \in \mathbb{C}$. Since every nonempty word in $A_i$ involves only the symbol $x_i$, the definition of $\varphi$ gives
\begin{align*}
\varphi(a)=c_0.
\end{align*}
In particular, $a \in A_i$ is centered, meaning $\varphi(a)=0$, exactly when its constant coefficient is $0$.
[/step]
[step:Verify freeness for each pair of subalgebras]
Fix distinct indices $i,j \in \{1,2,3\}$. We prove that $A_i$ and $A_j$ are free with respect to $\varphi$.
Let $r \in \mathbb{N}$, let $\varepsilon_1,\dots,\varepsilon_r \in \{i,j\}$ satisfy $\varepsilon_k \ne \varepsilon_{k+1}$ for every $k \in \{1,\dots,r-1\}$, and let $a_k \in A_{\varepsilon_k}$ satisfy $\varphi(a_k)=0$ for every $k$. By the previous step, each $a_k$ has zero constant coefficient, so each $a_k$ is a finite linear combination of positive powers of $x_{\varepsilon_k}$.
Therefore the product $a_1a_2\cdots a_r$ is a finite linear combination of nonempty words involving only the two symbols $x_i$ and $x_j$. By construction, $\varphi$ agrees with $\psi$ on every word involving at most two symbols, and $\psi$ vanishes on every nonempty word. Hence
\begin{align*}
\varphi(a_1a_2\cdots a_r)=0.
\end{align*}
This is exactly the alternating centered-word condition for freeness of $A_i$ and $A_j$. Since $i$ and $j$ were arbitrary distinct indices, the subalgebras $A_1,A_2,A_3$ are pairwise free.
[/step]
[step:Exhibit a centered alternating word whose mixed moment is nonzero]
For each $i \in \{1,2,3\}$, the generator $x_i$ lies in $A_i$ and is centered because $x_i$ is a nonempty one-letter word, so
\begin{align*}
\varphi(x_i)=0.
\end{align*}
The word $x_1x_2x_3$ is an alternating product of centered elements from $A_1,A_2,A_3$, since the adjacent subalgebras are distinct. If the family $(A_1,A_2,A_3)$ were free, the definition of freeness would force
\begin{align*}
\varphi(x_1x_2x_3)=0.
\end{align*}
But the construction of $\varphi$ gives
\begin{align*}
\varphi(x_1x_2x_3)=1.
\end{align*}
This contradiction shows that $A_1,A_2,A_3$ are not jointly free. Therefore pairwise freeness does not imply joint freeness.
[/step]