[proofplan]
Choose left symbols $a \in S^m(U \times \mathbb{R}^n)$ and $b \in S^{m'}(U \times \mathbb{R}^n)$ for $P$ and $Q$, modulo smoothing remainders. Proper support makes the composition globally defined on $U$, and the left-quantized composition formula supplies a left symbol $c \in S^{m+m'}(U \times \mathbb{R}^n)$ for $PQ$. The leading term of the asymptotic expansion of $c$ is $ab$, while every derivative term with positive multi-index has order at most $m+m'-1$. Passing to the quotient by $S^{m+m'-1}$ gives the product formula, and a final representative check shows that the product is independent of the chosen symbols.
[/proofplan]
[step:Choose left symbols representing the two operators]
Let $C_c^\infty(U)$ denote the space of complex-valued smooth functions with compact support in $U$, let $\mathcal{D}'(U)$ denote the space of complex-valued distributions on $U$, and let $\mathcal{L}^n$ denote $n$-dimensional [Lebesgue measure](/page/Lebesgue%20Measure) on $\mathbb{R}^n$. For any order $s \in \mathbb{R}$ and any complex-valued symbol $p \in S^s(U \times \mathbb{R}^n)$, define
\begin{align*}
\operatorname{Op}_L(p): C_c^\infty(U) \to \mathcal{D}'(U), \qquad u \mapsto (2\pi)^{-n}\int_U\int_{\mathbb{R}^n} e^{i(x-y)\cdot \xi}p(x,\xi)u(y)\,d\mathcal{L}^n(\xi)\,d\mathcal{L}^n(y)
\end{align*}
as the left-quantized local pseudodifferential operator, interpreted in the standard oscillatory sense. Since $P \in \Psi^m_{\mathrm{prop}}(U)$, choose a left symbol
\begin{align*}
a: U \times \mathbb{R}^n \to \mathbb{C}
\end{align*}
with $a \in S^m(U \times \mathbb{R}^n)$ such that $P-\operatorname{Op}_L(a)$ is smoothing. Since $Q \in \Psi^{m'}_{\mathrm{prop}}(U)$, choose a left symbol
\begin{align*}
b: U \times \mathbb{R}^n \to \mathbb{C}
\end{align*}
with $b \in S^{m'}(U \times \mathbb{R}^n)$ such that $Q-\operatorname{Op}_L(b)$ is smoothing. The principal symbol classes are therefore represented by
\begin{align*}
\sigma_m(P) = [a] \in S^m(U \times \mathbb{R}^n)/S^{m-1}(U \times \mathbb{R}^n)
\end{align*}
and
\begin{align*}
\sigma_{m'}(Q) = [b] \in S^{m'}(U \times \mathbb{R}^n)/S^{m'-1}(U \times \mathbb{R}^n).
\end{align*}
[/step]
[step:Use proper support to form the composition]
Because $P$ and $Q$ are properly supported, their Schwartz kernels have proper support over $U$ in both variables. Hence the usual kernel composition is well-defined on compactly supported distributions and produces a properly supported operator. Thus $PQ$ is a well-defined properly supported operator on $U$.
The hypotheses of the standard composition theorem in the properly supported left-quantized pseudodifferential calculus apply: $P$ and $Q$ are properly supported, and the preceding step represents them by left symbols $a \in S^m(U \times \mathbb{R}^n)$ and $b \in S^{m'}(U \times \mathbb{R}^n)$ modulo smoothing operators. Therefore the theorem states that $PQ \in \Psi^{m+m'}_{\mathrm{prop}}(U)$ and has a left symbol
\begin{align*}
c: U \times \mathbb{R}^n \to \mathbb{C}
\end{align*}
with $c \in S^{m+m'}(U \times \mathbb{R}^n)$ satisfying the asymptotic expansion
\begin{align*}
c(x,\xi) \sim \sum_{\alpha \in \mathbb{N}_0^n} \frac{1}{\alpha!}\partial_\xi^\alpha a(x,\xi)D_x^\alpha b(x,\xi).
\end{align*}
Here $\mathbb{N}_0 := \{0,1,2,\dots\}$, $\alpha = (\alpha_1,\dots,\alpha_n) \in \mathbb{N}_0^n$ is a multi-index, $\alpha! = \alpha_1!\cdots \alpha_n!$, $\partial_\xi^\alpha = \partial_{\xi_1}^{\alpha_1}\cdots\partial_{\xi_n}^{\alpha_n}$, and $D_x^\alpha$ denotes the left-quantization differential convention in the $x$ variable. The precise powers of $i$ in $D_x^\alpha$ affect only lower-order coefficients and not the leading term. This composition formula is the standard composition formula for left-quantized pseudodifferential operators in the local amplitude calculus.
[/step]
[step:Isolate the leading term in the composed symbol]
The term of the expansion corresponding to $\alpha = 0$ is exactly
\begin{align*}
\frac{1}{0!}\partial_\xi^0 a(x,\xi)D_x^0 b(x,\xi) = a(x,\xi)b(x,\xi).
\end{align*}
Since $a \in S^m(U \times \mathbb{R}^n)$ and $b \in S^{m'}(U \times \mathbb{R}^n)$, the product estimate for scalar symbols gives
\begin{align*}
ab \in S^{m+m'}(U \times \mathbb{R}^n).
\end{align*}
For every multi-index $\alpha \in \mathbb{N}_0^n$ with $|\alpha| \geq 1$, symbol differentiation gives
\begin{align*}
\partial_\xi^\alpha a \in S^{m-|\alpha|}(U \times \mathbb{R}^n)
\end{align*}
and
\begin{align*}
D_x^\alpha b \in S^{m'}(U \times \mathbb{R}^n).
\end{align*}
Multiplying these two symbol estimates yields
\begin{align*}
\partial_\xi^\alpha a \, D_x^\alpha b \in S^{m+m'-|\alpha|}(U \times \mathbb{R}^n) \subset S^{m+m'-1}(U \times \mathbb{R}^n).
\end{align*}
Thus all terms with $|\alpha| \geq 1$ contribute only to order at most $m+m'-1$.
[guided]
Recall that $a \in S^m(U \times \mathbb{R}^n)$ and $b \in S^{m'}(U \times \mathbb{R}^n)$ are complex-valued left symbols representing $P$ and $Q$ modulo smoothing operators, and that $c \in S^{m+m'}(U \times \mathbb{R}^n)$ is the left symbol for the composed operator $PQ$ supplied by the properly supported left-symbol composition theorem. The principal symbol only records the top-order part of the full symbol. Therefore we must identify which term in the composition expansion has order $m+m'$ and prove that every other term has strictly smaller order.
The expansion supplied by the left-symbol composition formula is
\begin{align*}
c(x,\xi) \sim \sum_{\alpha \in \mathbb{N}_0^n} \frac{1}{\alpha!}\partial_\xi^\alpha a(x,\xi)D_x^\alpha b(x,\xi).
\end{align*}
The multi-index $\alpha=0$ means $\partial_\xi^0$ and $D_x^0$ are the identity operators. Therefore the corresponding term is
\begin{align*}
\frac{1}{0!}\partial_\xi^0 a(x,\xi)D_x^0 b(x,\xi) = a(x,\xi)b(x,\xi).
\end{align*}
Because $a$ is a symbol of order $m$ and $b$ is a symbol of order $m'$, the symbol product estimate gives
\begin{align*}
ab \in S^{m+m'}(U \times \mathbb{R}^n).
\end{align*}
This is the only possible contributor to the principal symbol of order $m+m'$.
Now take a multi-index $\alpha \in \mathbb{N}_0^n$ with $|\alpha| \geq 1$. Differentiating a symbol in the frequency variable lowers its order by the number of frequency derivatives, so
\begin{align*}
\partial_\xi^\alpha a \in S^{m-|\alpha|}(U \times \mathbb{R}^n).
\end{align*}
Differentiating in the base variable $x$ does not lower the symbol order in the standard local symbol classes, so
\begin{align*}
D_x^\alpha b \in S^{m'}(U \times \mathbb{R}^n).
\end{align*}
Multiplying these two symbols gives
\begin{align*}
\partial_\xi^\alpha a \, D_x^\alpha b \in S^{m-|\alpha|+m'}(U \times \mathbb{R}^n).
\end{align*}
Since $|\alpha| \geq 1$, we have $m-|\alpha|+m' \leq m+m'-1$, and therefore
\begin{align*}
\partial_\xi^\alpha a \, D_x^\alpha b \in S^{m+m'-1}(U \times \mathbb{R}^n).
\end{align*}
Thus the derivative terms are invisible in the quotient by $S^{m+m'-1}(U \times \mathbb{R}^n)$. This is exactly why the principal symbol of a composition is just the product of the two principal symbols: the noncommutative correction terms begin one order lower.
[/guided]
[/step]
[step:Pass to the principal symbol quotient]
By the meaning of the asymptotic expansion for the composed symbol, subtracting the terms with $|\alpha| < 1$ leaves a remainder in $S^{m+m'-1}(U \times \mathbb{R}^n)$. Since the only term with $|\alpha| < 1$ is the term $ab$ identified in the preceding step, the composed left symbol $c$ satisfies
\begin{align*}
c - ab \in S^{m+m'-1}(U \times \mathbb{R}^n).
\end{align*}
Therefore the principal symbol class of $PQ$ is
\begin{align*}
\sigma_{m+m'}(PQ) = [c] = [ab]
\end{align*}
in $S^{m+m'}(U \times \mathbb{R}^n)/S^{m+m'-1}(U \times \mathbb{R}^n)$.
[/step]
[step:Check that the product does not depend on the chosen representatives]
Let $a_1 \in S^m(U \times \mathbb{R}^n)$ be another representative of $\sigma_m(P)$ and let $b_1 \in S^{m'}(U \times \mathbb{R}^n)$ be another representative of $\sigma_{m'}(Q)$. Then
\begin{align*}
a_1-a \in S^{m-1}(U \times \mathbb{R}^n)
\end{align*}
and
\begin{align*}
b_1-b \in S^{m'-1}(U \times \mathbb{R}^n).
\end{align*}
Using bilinearity of multiplication, write
\begin{align*}
a_1b_1-ab = (a_1-a)b + a(b_1-b) + (a_1-a)(b_1-b).
\end{align*}
The symbol product estimates give
\begin{align*}
(a_1-a)b \in S^{m+m'-1}(U \times \mathbb{R}^n),
\end{align*}
\begin{align*}
a(b_1-b) \in S^{m+m'-1}(U \times \mathbb{R}^n),
\end{align*}
and
\begin{align*}
(a_1-a)(b_1-b) \in S^{m+m'-2}(U \times \mathbb{R}^n) \subset S^{m+m'-1}(U \times \mathbb{R}^n).
\end{align*}
Hence
\begin{align*}
a_1b_1-ab \in S^{m+m'-1}(U \times \mathbb{R}^n).
\end{align*}
Thus $[ab]$ depends only on $[a]$ and $[b]$. Combining this with the previous step gives
\begin{align*}
\sigma_{m+m'}(PQ) = \sigma_m(P)\sigma_{m'}(Q)
\end{align*}
in $S^{m+m'}(U \times \mathbb{R}^n)/S^{m+m'-1}(U \times \mathbb{R}^n)$, as claimed.
[/step]