[proofplan]
The proof is a direct unpacking of the definition of the trace pairing. We write both values of $B_{K/k}$ as field traces of products in $K$. Since $K$ is a field, multiplication in $K$ is commutative, so the two products have the same trace.
[/proofplan]
[step:Expand the trace pairing on both ordered pairs]
Let $\alpha,\beta \in K$. By the definition of the trace pairing $B_{K/k}:K \times K \to k$, we have
\begin{align*}
B_{K/k}(\alpha,\beta)=\operatorname{Tr}_{K/k}(\alpha\beta).
\end{align*}
Similarly,
\begin{align*}
B_{K/k}(\beta,\alpha)=\operatorname{Tr}_{K/k}(\beta\alpha).
\end{align*}
[guided]
Fix arbitrary elements $\alpha,\beta \in K$. The trace pairing is the map
\begin{align*}
B_{K/k}: K \times K \to k
\end{align*}
defined by sending an ordered pair $(\gamma,\delta) \in K \times K$ to the field trace of the product $\gamma\delta$:
\begin{align*}
B_{K/k}(\gamma,\delta)=\operatorname{Tr}_{K/k}(\gamma\delta).
\end{align*}
Applying this definition first to the ordered pair $(\alpha,\beta)$ gives
\begin{align*}
B_{K/k}(\alpha,\beta)=\operatorname{Tr}_{K/k}(\alpha\beta).
\end{align*}
Applying the same definition to the reversed ordered pair $(\beta,\alpha)$ gives
\begin{align*}
B_{K/k}(\beta,\alpha)=\operatorname{Tr}_{K/k}(\beta\alpha).
\end{align*}
Thus the desired symmetry reduces to comparing the two products $\alpha\beta$ and $\beta\alpha$ inside the field $K$.
[/guided]
[/step]
[step:Use commutativity of multiplication in $K$]
Since $K$ is a field, multiplication in $K$ is commutative. Therefore
\begin{align*}
\alpha\beta=\beta\alpha.
\end{align*}
Applying the function $\operatorname{Tr}_{K/k}:K \to k$ to this equality gives
\begin{align*}
\operatorname{Tr}_{K/k}(\alpha\beta)=\operatorname{Tr}_{K/k}(\beta\alpha).
\end{align*}
Combining this equality with the two expansions above yields
\begin{align*}
B_{K/k}(\alpha,\beta)=B_{K/k}(\beta,\alpha).
\end{align*}
Because $\alpha,\beta \in K$ were arbitrary, the trace pairing is symmetric on $K \times K$.
[/step]