[proofplan]
We first check that the Bott-Chern-to-Aeppli map is meaningful and then prove the central equivalence: injectivity of this map is exactly the statement that a pure-type form which is both $\partial$-closed, $\bar{\partial}$-closed, and Aeppli-exact is already $\partial\bar{\partial}$-exact. This avoids the invalid inference that a single bidegree component of a $d$-exact form is itself $d$-exact. The de Rham representative formulation is then identified through the Bott-Chern-de Rham comparison theorem stated in the formalized statement, which is the compactness-dependent input relating the cohomological $\partial\bar{\partial}$ lemma to the Bott-Chern-to-de Rham comparison maps.
[/proofplan]
[step:Verify that the comparison map is well-defined]
Let $\alpha\in A^{p,q}(X)$ represent a Bott-Chern class. By definition, $\partial\alpha=0$ and $\bar{\partial}\alpha=0$. Therefore
\begin{align*}
\partial\bar{\partial}\alpha=0,
\end{align*}
so $\alpha$ also defines an Aeppli class.
If $\alpha$ and $\alpha'$ represent the same Bott-Chern class, then there exists $\gamma\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\alpha'-\alpha=\partial\bar{\partial}\gamma.
\end{align*}
Since $\partial\bar{\partial}\gamma=\partial(\bar{\partial}\gamma)$ lies in $\partial A^{p-1,q}(X)$, it is zero in Aeppli cohomology. Hence $[\alpha']_A=[\alpha]_A$, so $\iota_{p,q}$ is well-defined.
[/step]
[step:Show that the cohomological $\partial\bar{\partial}$ lemma implies injectivity of the comparison maps]
Assume the cohomological $\partial\bar{\partial}$ lemma. Fix $p,q\ge 0$, and let $[\alpha]_{BC}\in H^{p,q}_{BC}(X)$ satisfy
\begin{align*}
\iota_{p,q}([\alpha]_{BC})=0.
\end{align*}
Choose a representative $\alpha\in A^{p,q}(X)$ with $\partial\alpha=0$ and $\bar{\partial}\alpha=0$. The equality $\iota_{p,q}([\alpha]_{BC})=0$ means that $[\alpha]_A=0$ in $H_A^{p,q}(X)$. By the definition of the Aeppli quotient, there exist forms $\mu\in A^{p-1,q}(X)$ and $\nu\in A^{p,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\mu+\bar{\partial}\nu.
\end{align*}
Thus $\alpha\in \partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X)$, while the Bott-Chern representative conditions give $\partial\alpha=0$ and $\bar{\partial}\alpha=0$. The cohomological $\partial\bar{\partial}$ lemma therefore applies directly to $\alpha$ and gives a form $\gamma\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\bar{\partial}\gamma.
\end{align*}
Hence $[\alpha]_{BC}=0$, so $\iota_{p,q}$ is injective.
[/step]
[step:Use injectivity to recover the cohomological $\partial\bar{\partial}$ lemma]
Assume that $\iota_{p,q}$ is injective for every $p,q\ge 0$. Let $\alpha\in A^{p,q}(X)$ satisfy $\partial\alpha=0$, $\bar{\partial}\alpha=0$, and
\begin{align*}
\alpha\in \partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X).
\end{align*}
The first two equalities say that $\alpha$ represents a Bott-Chern class $[\alpha]_{BC}\in H^{p,q}_{BC}(X)$. The membership condition means that there exist forms $\mu\in A^{p-1,q}(X)$ and $\nu\in A^{p,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\mu+\bar{\partial}\nu.
\end{align*}
Thus $[\alpha]_A=0$ in $H_A^{p,q}(X)$. Since $\iota_{p,q}$ is injective and $\iota_{p,q}([\alpha]_{BC})=[\alpha]_A=0$, we obtain $[\alpha]_{BC}=0$. By the definition of Bott-Chern cohomology, there exists $\gamma\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\bar{\partial}\gamma.
\end{align*}
This is precisely the cohomological $\partial\bar{\partial}$ lemma.
[guided]
Assume that every comparison map $\iota_{p,q}$ is injective. We want to prove the cohomological $\partial\bar{\partial}$ lemma, so we begin with a pure-type form $\alpha\in A^{p,q}(X)$ satisfying
\begin{align*}
\partial\alpha=0
\end{align*}
and
\begin{align*}
\bar{\partial}\alpha=0
\end{align*}
and
\begin{align*}
\alpha\in \partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X).
\end{align*}
The two closedness conditions are exactly the numerator conditions in Bott-Chern cohomology, so $\alpha$ defines a class $[\alpha]_{BC}\in H^{p,q}_{BC}(X)$.
Now use the Aeppli-exactness hypothesis. The statement
\begin{align*}
\alpha\in \partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X)
\end{align*}
means that there are forms $\mu\in A^{p-1,q}(X)$ and $\nu\in A^{p,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\mu+\bar{\partial}\nu.
\end{align*}
This equality says exactly that $\alpha$ is zero in Aeppli cohomology, because the denominator of $H_A^{p,q}(X)$ is $\partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X)$. Therefore
\begin{align*}
\iota_{p,q}([\alpha]_{BC})=[\alpha]_A=0.
\end{align*}
By the assumed injectivity of $\iota_{p,q}$, this forces $[\alpha]_{BC}=0$. Finally, the meaning of $[\alpha]_{BC}=0$ is precisely that $\alpha$ lies in the image of $\partial\bar{\partial}$: there exists $\gamma\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\bar{\partial}\gamma.
\end{align*}
This proves the cohomological $\partial\bar{\partial}$ lemma.
[/guided]
[/step]
[step:Deduce the pure-type de Rham representative statement]
Assume the equivalent conditions already proved. We use the Bott-Chern-de Rham comparison theorem in the precise form included in the statement: on the compact complex manifold $X$ of complex dimension $n$ satisfying the cohomological $\partial\bar{\partial}$ lemma, for every integer $k$ with $0\le k\le 2n$ the map $\Phi_k:\bigoplus_{p+q=k}H^{p,q}_{BC}(X)\to H^k_{dR}(X;\mathbb C)$ defined by
\begin{align*}
\Phi_k\left(\sum_{p+q=k}[\alpha^{p,q}]_{BC}\right)=\left[\sum_{p+q=k}\alpha^{p,q}\right]_{dR}
\end{align*}
is an isomorphism. The hypotheses of this comparison theorem match the present situation: $X$ is compact complex by assumption, $0\le k\le 2n$, and the cohomological $\partial\bar{\partial}$ lemma is the equivalent condition established in the preceding steps. The map is well-defined because every Bott-Chern representative is both $\partial$-closed and $\bar{\partial}$-closed, hence $d$-closed by the type decomposition $d=\partial+\bar{\partial}$ for forms on the complex manifold $X$ from [citetheorem:7004]. If $\alpha^{p,q}$ is changed by $\partial\bar{\partial}\gamma^{p-1,q-1}$, then [citetheorem:8046] gives $\bar{\partial}^2=0$, so under the convention $d=\partial+\bar{\partial}$ the total form changes by the $d$-exact form $d(\bar{\partial}\gamma^{p-1,q-1})=\partial\bar{\partial}\gamma^{p-1,q-1}$.
Surjectivity of $\Phi_k$ gives, for every de Rham class $[\beta]\in H^k_{dR}(X;\mathbb C)$, Bott-Chern classes $[\beta^{p,q}]_{BC}\in H^{p,q}_{BC}(X)$ such that
\begin{align*}
[\beta]=\left[\sum_{p+q=k}\beta^{p,q}\right]_{dR}.
\end{align*}
Choosing Bott-Chern representatives $\beta^{p,q}\in A^{p,q}(X)$ gives $\partial\beta^{p,q}=0$ and $\bar{\partial}\beta^{p,q}=0$, hence $d\beta^{p,q}=0$ by [citetheorem:7004]. Thus
\begin{align*}
\beta'=\sum_{p+q=k}\beta^{p,q}
\end{align*}
is a representative of $[\beta]$ whose pure-type components are all $d$-closed.
For uniqueness, suppose
\begin{align*}
\sum_{p+q=k}\beta^{p,q}
\end{align*}
and
\begin{align*}
\sum_{p+q=k}\widetilde{\beta}^{p,q}
\end{align*}
are two such representatives of the same de Rham class. For each $p+q=k$, define
\begin{align*}
\delta^{p,q}:=\beta^{p,q}-\widetilde{\beta}^{p,q}\in A^{p,q}(X).
\end{align*}
Since both components are $d$-closed, [citetheorem:7004] implies $\partial\delta^{p,q}=0$ and $\bar{\partial}\delta^{p,q}=0$, so $\delta^{p,q}$ defines a Bott-Chern class. The equality of de Rham classes says
\begin{align*}
\Phi_k\left(\sum_{p+q=k}[\delta^{p,q}]_{BC}\right)=0.
\end{align*}
Injectivity of $\Phi_k$ gives $[\delta^{p,q}]_{BC}=0$ for every $p+q=k$. By the definition of Bott-Chern cohomology, for every $p+q=k$ there exists $\gamma^{p-1,q-1}\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\beta^{p,q}-\widetilde{\beta}^{p,q}=\partial\bar{\partial}\gamma^{p-1,q-1}.
\end{align*}
[/step]
[step:Recover the cohomological $\partial\bar{\partial}$ lemma from the Bott-Chern-de Rham comparison]
Assume the de Rham comparison condition, namely that for every integer $k$ with $0\le k\le 2n$ the map
\begin{align*}
\Phi_k:\bigoplus_{p+q=k}H^{p,q}_{BC}(X)\longrightarrow H^k_{dR}(X;\mathbb C)
\end{align*}
is an isomorphism. The converse direction of the Bott-Chern-de Rham comparison theorem stated in the formalized statement applies to the compact complex manifold $X$: if all maps $\Phi_k$ are isomorphisms, then the cohomological $\partial\bar{\partial}$ lemma holds on $X$. Its hypotheses are exactly the compact complex manifold hypothesis and the isomorphism condition just assumed.
For completeness, this means that whenever $\alpha\in A^{p,q}(X)$ satisfies $\partial\alpha=0$, $\bar{\partial}\alpha=0$, and
\begin{align*}
\alpha\in \partial A^{p-1,q}(X)+\bar{\partial}A^{p,q-1}(X),
\end{align*}
there exists $\gamma\in A^{p-1,q-1}(X)$ such that
\begin{align*}
\alpha=\partial\bar{\partial}\gamma.
\end{align*}
By the equivalence already proved between the cohomological $\partial\bar{\partial}$ lemma and injectivity of the maps $\iota_{p,q}$, the comparison maps $\iota_{p,q}$ are injective for every $p,q\ge 0$. Combining the previous steps proves the equivalence of all three formulations.
[/step]