[example: A Non-Injective Discrete Random Variable]
Let $\Omega=\{1,2,3,4\}$, let $\mathcal F$ be the power set of $\Omega$, and suppose each outcome has probability $1/4$. Define $X:\Omega\to\mathbb R$ by $X(1)=0$, $X(2)=0$, $X(3)=1$, and $X(4)=3$. The range of $X$ is $\{0,1,3\}$, which is finite and therefore countable, so $X$ is a discrete random variable.
The mass at $0$ is the probability of the inverse image of $\{0\}$:
\begin{align*}
\{X=0\}=\{\omega\in\Omega:X(\omega)=0\}=\{1,2\}.
\end{align*}
Since the two outcomes $1$ and $2$ are disjoint and each has probability $1/4$,
\begin{align*}
p_X(0)=\mathbb P(X=0)=\mathbb P(\{1,2\})=\mathbb P(\{1\})+\mathbb P(\{2\})=\frac{1}{4}+\frac{1}{4}=\frac{1}{2}.
\end{align*}
Similarly,
\begin{align*}
\{X=1\}=\{3\},
\end{align*}
so
\begin{align*}
p_X(1)=\mathbb P(X=1)=\mathbb P(\{3\})=\frac{1}{4}.
\end{align*}
Also,
\begin{align*}
\{X=3\}=\{4\},
\end{align*}
so
\begin{align*}
p_X(3)=\mathbb P(X=3)=\mathbb P(\{4\})=\frac{1}{4}.
\end{align*}
If $x\notin\{0,1,3\}$, then no outcome is mapped to $x$, hence
\begin{align*}
\{X=x\}=\varnothing
\end{align*}
and therefore
\begin{align*}
p_X(x)=\mathbb P(X=x)=\mathbb P(\varnothing)=0.
\end{align*}
Thus $\operatorname{supp}(X)=\{0,1,3\}$. The value $0$ has larger mass than $1$ or $3$ because two distinct sample outcomes are merged into the same value of the random variable.
[/example]