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**Step 1: Well-definedness.** Let $\varphi \in \mathcal{D}(\Omega)$. Since $\mathrm{supp}(\varphi) \subset (0,1)$ is compact, there exists $\varepsilon > 0$ such that $\mathrm{supp}(\varphi) \subseteq [\varepsilon, 1 - \varepsilon]$. For all $k$ with $1/k < \varepsilon$ (i.e. $k > 1/\varepsilon$), the point $1/k$ lies outside $\mathrm{supp}(\varphi)$, so $\varphi'(1/k) = 0$. Hence the sum is finite — it has at most $\lfloor 1/\varepsilon \rfloor$ nonzero terms — and $T(\varphi)$ is a well-defined real number.
Linearity is immediate from linearity of differentiation and finite sums. For continuity, suppose $\varphi_j \to 0$ in $\mathcal{D}(\Omega)$ with all supports in a compact set $K \subset (0, 1)$. Then $K \subseteq [\varepsilon, 1 - \varepsilon]$ for some $\varepsilon > 0$, and the sum $T(\varphi_j) = \sum_{k: 1/k \in K} \varphi_j'(1/k)$ has a fixed finite number of terms (independent of $j$). Since $\varphi_j' \to 0$ uniformly, each term $\varphi_j'(1/k) \to 0$, so $T(\varphi_j) \to 0$.
**Step 2: Singularity.** Suppose for contradiction that $T = T_f$ for some $f \in L^1_\mathrm{loc}(\Omega)$, so that $\int_0^1 f \varphi \, d\mathcal{L}^1 = \sum_k \varphi'(1/k)$ for all $\varphi \in \mathcal{D}(\Omega)$. Choose $\varphi \in \mathcal{D}(\Omega)$ supported in $(1/3, 1/2)$ with $\varphi' \not\equiv 0$. The only $k$ with $1/k \in (1/3, 1/2)$ are $k = 3$ (giving $1/3$, on the boundary) — but $\mathrm{supp}(\varphi) \subset (1/3, 1/2)$ is open, so $\varphi(1/3) = \varphi'(1/3) = 0$, and $T(\varphi) = 0$. Thus $\int_{1/3}^{1/2} f \varphi \, d\mathcal{L}^1 = 0$ for all such $\varphi$, which forces $f = 0$ a.e. on $(1/3, 1/2)$.
By the same argument applied to intervals $(1/(k+1), 1/k)$ for each $k \geq 2$, we get $f = 0$ a.e. on each such interval, hence $f = 0$ a.e. on $(0, 1)$. But then $T = T_0 = 0$, which is false since $T(\varphi) = \varphi'(1)$ for any $\varphi$ with support near $x = 1$ and away from all other $1/k$. This contradicts $T = T_f$, so $T$ is singular.
**Step 3: Support.** From Step 1, $T(\varphi) = 0$ whenever $\mathrm{supp}(\varphi)$ is disjoint from the set $\{1/k : k \in \mathbb{N}\}$. The closure of this set in $(0,1)$ is $\{0\} \cup \{1/k : k \in \mathbb{N}\}$, but $0 \notin \Omega = (0, 1)$, so the closure within $\Omega$ is $\{1/k : k \in \mathbb{N}\}$ (which is closed in $(0,1)$ since its only accumulation point, $0$, is outside $\Omega$). If $x_0 \notin \{1/k : k \in \mathbb{N}\}$ and $x_0 \in (0, 1)$, then $x_0$ has a neighbourhood $U \subseteq (0,1)$ disjoint from $\{1/k\}$, so $T(\varphi) = 0$ for all $\varphi \in \mathcal{D}(U)$. Conversely, for each $1/k$, there exist test functions supported near $1/k$ with $\varphi'(1/k) \neq 0$. Therefore $\mathrm{supp}(T) = \{1/k : k \in \mathbb{N}\}$.
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