[solution]
Let $u = \delta_0$, the Dirac delta at the origin. This is singular (proved in the example above). Its distributional derivative $\delta_0'$ is defined by $\delta_0'(\varphi) = -\varphi'(0)$. This is also singular (it has order $1$, but more directly: no $L^1_{\mathrm{loc}}$ function can reproduce $-\varphi'(0)$ by integration). So this does not work.
Instead, consider $u = T_H$ where $H(x) = \mathbb{1}_{[0,\infty)}(x)$ is the Heaviside function. Then $u$ is a regular distribution. Its distributional derivative $u' = \delta_0$ is singular. This gives the reverse — a regular distribution with singular derivative. The problem asks for the other direction.
Take $u(x) = \log|x|$ on $\mathbb{R}$. This is locally integrable (the singularity $\log|x|$ is integrable near $0$ in one dimension), so $T_{\log|\cdot|} \in \mathcal{D}'(\mathbb{R})$ is regular. Its distributional derivative is $T_{\log|\cdot|}'(\varphi) = -\int \log|x| \, \varphi'(x) \, d\mathcal{L}^1(x) = \int \frac{\varphi(x)}{x} \, d\mathcal{L}^1(x)$ (integrating by parts, using $(\log|x|)' = 1/x$ for $x \ne 0$), but $1/x$ is not locally integrable near $0$. The derivative is the **principal value distribution** $\mathrm{p.v.}(1/x)$, defined by $\mathrm{p.v.}(1/x)(\varphi) = \lim_{\varepsilon \to 0^+}\int_{|x|>\varepsilon} \varphi(x)/x \, d\mathcal{L}^1(x)$. This is singular: $1/x \notin L^1_{\mathrm{loc}}(\mathbb{R})$.
So actually the problem as stated asks for the *reverse*: $u$ singular, $u'$ regular. Consider $u = \mathrm{sgn}(x) = 2H(x) - 1$. Then $u$ is regular (it is bounded, hence locally integrable). And $u' = 2\delta_0$, which is singular. Still wrong direction.
Consider instead: $u = \delta_0 * H$ does not help either. Let us construct directly. Define $u \in \mathcal{D}'(\mathbb{R})$ by $u = \sum_{k=1}^\infty 2^{-k} \delta_{1/k}$. This is a distribution (the sum converges in $\mathcal{D}'$ since any compact set contains only finitely many of the points $1/k$). It is singular — it is a countable sum of point masses, which is a measure that is not absolutely continuous with respect to $\mathcal{L}^1$. Its distributional derivative is $u' = \sum_{k=1}^\infty 2^{-k}\delta_{1/k}'$, which is also singular.
A simpler approach: the problem has no solution in the stated direction. If $u$ is singular and $u'$ is regular, say $u' = T_g$ for some $g \in L^1_{\mathrm{loc}}(\mathbb{R})$, then (at least on any bounded interval) $u = T_G + c\delta_0 + \ldots$ where $G$ is an antiderivative of $g$ — but this needs care. In fact, if $u' = T_g$ with $g \in L^1_{\mathrm{loc}}$, then on any bounded interval $u$ equals $T_G$ for some antiderivative $G(x) = \int_a^x g(t) \, dt + c$, which is absolutely continuous, hence locally integrable, so $u$ is regular on every bounded interval, and therefore regular globally. This is a contradiction: **if $u'$ is regular, then $u$ is regular.** So no such example exists.
The correct answer is: **no such $u$ exists.** If the distributional derivative $u'$ is a regular distribution $T_g$ with $g \in L^1_{\mathrm{loc}}(\mathbb{R})$, then on any interval $(a, b)$, the function $G(x) := \int_a^x g(t) \, dt$ satisfies $T_G' = T_g = u'$ in $\mathcal{D}'((a,b))$. Since $(u - T_G)' = 0$ on $(a,b)$, the distribution $u - T_G$ is a constant $c_{a,b}$ on $(a,b)$ (distributions with zero derivative on a connected open set are constants). Thus $u = T_{G + c_{a,b}}$ on $(a,b)$, meaning $u$ is regular on every bounded interval, and therefore on all of $\mathbb{R}$. So: a distribution on $\mathbb{R}$ whose derivative is regular is itself regular.
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