[guided]We use the inner product characterisation of the WOT on a Hilbert space. On $\mathcal{L}(H, H)$, the WOT is generated by the seminorms $T \mapsto |(Tx, y)_H|$ for $x, y \in H$. This is because the [Riesz Representation Theorem](/theorems/218) identifies every $f \in H^*$ with a unique $y_f \in H$ via $f(\cdot) = (\cdot, y_f)_H$, so $f(Tx) = (Tx, y_f)_H$.
Fix $x, y \in H$. We need $(T_\alpha^* x, y)_H \to (T^* x, y)_H$. The key is the symmetry of the inner product via the adjoint:
\begin{align*}
(T_\alpha^* x, y)_H = (x, T_\alpha y)_H = \overline{(T_\alpha y, x)_H}.
\end{align*}
The WOT convergence $T_\alpha \to T$ evaluated at the vector $y \in H$ and the functional $(\cdot, x)_H \in H^*$ gives
\begin{align*}
(T_\alpha y, x)_H \to (Ty, x)_H.
\end{align*}
Since complex conjugation is a continuous operation on $\mathbb{C}$ (or the identity on $\mathbb{R}$),
\begin{align*}
(T_\alpha^* x, y)_H = \overline{(T_\alpha y, x)_H} \to \overline{(Ty, x)_H} = (x, Ty)_H = (T^* x, y)_H.
\end{align*}
Since $x, y \in H$ were arbitrary, $T_\alpha^* \to T^*$ in the WOT.
The essential feature of Hilbert spaces used here is that the WOT is determined by the inner product, and the adjoint simply swaps the two arguments of the inner product. This swap is invisible in the WOT because WOT convergence quantifies over *all* pairs $(x, y)$.[/guided]