[step:Form the residue field $F = k[X_1, \ldots, X_n]/\mathfrak{m}$ and reduce the claim to showing $F = k$]
Since $\mathfrak{m}$ is a maximal ideal of the commutative ring $k[X_1, \ldots, X_n]$, the quotient
\begin{align*}
F := k[X_1, \ldots, X_n]/\mathfrak{m}
\end{align*}
is a field. The composition
\begin{align*}
\iota : k \hookrightarrow k[X_1, \ldots, X_n] \twoheadrightarrow F
\end{align*}
is a ring homomorphism between fields, hence injective (its kernel is a proper ideal of $k$, which has only $0$ and $k$ as ideals; the image of $1$ is non-zero, so the kernel is $0$). We identify $k$ with $\iota(k) \subset F$ and view $F$ as a field extension of $k$.
\textbf{Suppose for now that $F = k$.} Then for each $i$, the residue class $X_i \bmod \mathfrak{m}$ lies in $k \subset F$; call it $a_i \in k$. By definition of the quotient, $X_i - a_i \in \mathfrak{m}$ for each $i$, so
\begin{align*}
(X_1 - a_1, \ldots, X_n - a_n) \subset \mathfrak{m}.
\end{align*}
Conversely, $(X_1 - a_1, \ldots, X_n - a_n)$ is itself a maximal ideal: the quotient
\begin{align*}
k[X_1, \ldots, X_n]/(X_1 - a_1, \ldots, X_n - a_n) \cong k
\end{align*}
via the evaluation map $f(X_1, \ldots, X_n) \mapsto f(a_1, \ldots, a_n)$ (well-defined since the kernel is exactly the ideal of polynomials vanishing at $a$, which contains every $X_i - a_i$). Since $(X_1 - a_1, \ldots, X_n - a_n)$ is maximal and contained in the proper ideal $\mathfrak{m}$, equality holds:
\begin{align*}
\mathfrak{m} = (X_1 - a_1, \ldots, X_n - a_n).
\end{align*}
The remaining task is therefore to prove $F = k$.
[/step]