[step:Extend $\Phi$ from simples to $L^\infty(P)$ by density and continuity]
The space $\mathcal{S}(K)$ of simple Borel functions is dense in $L^\infty(P)$ in the $L^\infty(P)$-norm. (This is a standard fact: any bounded Borel function $f$ is a uniform limit of simple Borel functions, by partitioning the range $\{|f| \le \|f\|_\infty\}$ into small Borel pieces $E_i^{(n)} := f^{-1}(B_i^{(n)})$ for shrinking partitions $\{B_i^{(n)}\}$ of the range and forming $s_n := \sum_i c_i^{(n)} \mathbb{1}_{E_i^{(n)}}$ with $c_i^{(n)}$ a value sampled from $B_i^{(n)}$; then $\|f - s_n\|_\infty \le \operatorname{diam}(B_i^{(n)}) \to 0$.)
Since $\Phi: \mathcal{S}(K) \to \mathcal{L}(H)$ is linear and isometric (Step 5), and $\mathcal{L}(H)$ is complete, $\Phi$ extends uniquely to a bounded linear isometric map
\begin{align*}
\Phi: L^\infty(P) \to \mathcal{L}(H).
\end{align*}
Call this extension $\Phi$ as well.
*Algebraic properties persist.* The unital $*$-homomorphism identities $\Phi(1) = I$, $\Phi(\bar{f}) = \Phi(f)^*$, $\Phi(fg) = \Phi(f) \Phi(g)$ hold on $\mathcal{S}(K)$ (Step 3); by continuity of $\Phi$, the involution $A \mapsto A^*$ on $\mathcal{L}(H)$, and operator multiplication (jointly continuous on bounded sets), they extend to all of $L^\infty(P)$.
*Property (i) on $L^\infty(P)$.* Fix $x, y \in H$. The map $f \mapsto (\Phi(f)x, y)_H$ is a bounded linear functional on $L^\infty(P)$ (composition of $\Phi$ with the bounded inner-product evaluation). The map $f \mapsto \int_K f \, dP_{x,y}$ is also a bounded linear functional on $L^\infty(P)$, by axiom (R5) which gives $|\int_K f \, dP_{x,y}| \le \|f\|_\infty \|P_{x,y}\|_1 \le \|f\|_\infty \|x\|_H \|y\|_H$. The two functionals agree on simples by Step 4. Two bounded linear functionals that agree on a dense subspace agree everywhere. Hence formula (i) holds on $L^\infty(P)$.
*Property (ii) on $L^\infty(P)$.* For any $f \in L^\infty(P)$, $|f|^2 \in L^\infty(P)$, and applying property (i) to $|f|^2$ with $y = x$:
\begin{align*}
\|\Phi(f)x\|_H^2 = (\Phi(f)^*\Phi(f)x, x)_H = (\Phi(\bar{f} f)x, x)_H = (\Phi(|f|^2)x, x)_H = \int_K |f|^2 \, dP_{x,x}.
\end{align*}
Uniqueness of $\Phi$ as an isometric, unital $*$-homomorphism $L^\infty(P) \to \mathcal{L}(H)$ satisfying (i): the value of $\Phi$ on simples is determined by (i) (specialised to characteristic functions: $(\Phi(\mathbb{1}_E)x, y)_H = P_{x,y}(E) = (P(E)x, y)_H$, so $\Phi(\mathbb{1}_E) = P(E)$, and linearity extends this to all simples), and continuity then determines $\Phi$ on $L^\infty(P)$ by density.
[/step]