[guided]We use [De Giorgi's Structure Theorem](/theorems/599) to express $D\mathbb{1}_E$ in concrete terms, then substitute into the identity from Step 1.
*Polar decomposition of a vector-valued Radon measure.* Any $\mathbb{R}^n$-valued Radon measure $\mu$ on $\Omega$ admits a polar decomposition
\begin{align*}
\mu = \nu_\mu \cdot |\mu|,
\end{align*}
where $|\mu|$ is the total variation (a non-negative Radon measure) and $\nu_\mu = d\mu / d|\mu|: \Omega \to S^{n-1}$ is a Borel-measurable unit vector field, defined $|\mu|$-a.e. by the Radon-Nikodym theorem.
*Applying De Giorgi to $\mu = D\mathbb{1}_E$.* The hypothesis of [De Giorgi's Structure Theorem](/theorems/599) is that $E \subseteq \mathbb{R}^n$ is a Borel set of finite perimeter, which is given. The theorem yields:
- Part (c): $|D\mathbb{1}_E|(A) = \mathcal{H}^{n-1}(A \cap \partial^* E)$ for every Borel $A$, so $|D\mathbb{1}_E| = \mathcal{H}^{n-1}\lfloor \partial^* E$.
- Part (d): the Radon-Nikodym derivative $dD\mathbb{1}_E / d|D\mathbb{1}_E|$ at $\mathcal{H}^{n-1}$-a.e. $x \in \partial^* E$ is $-\nu_E(x)$ — the minus sign coming from the convention that $\nu_E$ is the *outer* unit normal (the direction in which $\mathbb{1}_E$ decreases, opposite to the gradient direction which records the increase).
Combining the two parts:
\begin{align*}
D\mathbb{1}_E = \frac{dD\mathbb{1}_E}{d|D\mathbb{1}_E|} \cdot |D\mathbb{1}_E| = (-\nu_E) \cdot \big(\mathcal{H}^{n-1}\lfloor \partial^* E\big) = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \partial^* E.
\end{align*}
This is the explicit form of $D\mathbb{1}_E$ as a vector-valued Radon measure on $\Omega$.
*Action on $\phi$.* For $\phi \in C_c^1(\Omega; \mathbb{R}^n)$, the action of $D\mathbb{1}_E$ on $\phi$ is the integral
\begin{align*}
\int_\Omega \phi(x) \cdot dD\mathbb{1}_E(x) = \int_\Omega \phi(x) \cdot (-\nu_E(x)) \, d\big(\mathcal{H}^{n-1}\lfloor \partial^* E\big)(x) = -\int_{\partial^* E \cap \Omega} \phi(x) \cdot \nu_E(x) \, d\mathcal{H}^{n-1}(x).
\end{align*}
The restriction notation $\mathcal{H}^{n-1}\lfloor \partial^* E$ means we integrate against $\mathcal{H}^{n-1}$ over the set $\partial^* E$; the intersection with $\Omega$ comes from the support of $\phi$ being in $\Omega$. (The integrand $\phi \cdot \nu_E$ is well-defined $\mathcal{H}^{n-1}$-a.e. on $\partial^* E$ because $\nu_E$ is defined $\mathcal{H}^{n-1}$-a.e. on $\partial^* E$ as part of the structure theorem.)
*Substitution into Step 1's identity.* From Step 1,
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = -\int_\Omega \phi \cdot dD\mathbb{1}_E.
\end{align*}
Substituting the formula above:
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = -\left( -\int_{\partial^* E \cap \Omega} \phi \cdot \nu_E \, d\mathcal{H}^{n-1} \right) = \int_{\partial^* E \cap \Omega} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}.
\end{align*}
*Removing the explicit $\Omega$-restriction.* Because $\phi \in C_c^1(\Omega; \mathbb{R}^n)$ has compact support in $\Omega$, it vanishes outside $\Omega$. Hence
\begin{align*}
\int_{\partial^* E \cap \Omega} \phi \cdot \nu_E \, d\mathcal{H}^{n-1} = \int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1},
\end{align*}
the integrand vanishing $\mathcal{H}^{n-1}$-a.e. on $\partial^* E \setminus \Omega$.
*Conclusion.* We have shown
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = \int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}
\end{align*}
for every $\phi \in C_c^1(\Omega; \mathbb{R}^n)$, which is the Gauss-Green theorem for sets of finite perimeter. The proof is complete.
*Remark on the sign convention.* The minus sign in the polar decomposition $D\mathbb{1}_E = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \partial^* E$ is the only delicate point. To verify the convention: take the simple example $E = \{x_n < 0\}$ in $\mathbb{R}^n$. The classical outer normal is $\nu_E = e_n$ (pointing into $\{x_n > 0\}$). The distributional gradient $D\mathbb{1}_E$ is computed against $\phi = (\phi_1, \ldots, \phi_n) \in C_c^1$:
\begin{align*}
D\mathbb{1}_E(\phi) = -\int_{\{x_n < 0\}} \operatorname{div} \phi \, d\mathcal{L}^n = -\int_{\mathbb{R}^{n-1}} \phi_n(x', 0) \, d\mathcal{L}^{n-1}(x') = -\int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}(x'),
\end{align*}
the second equality from integrating in $x_n$ over $(-\infty, 0)$. Therefore $D\mathbb{1}_E = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \{x_n = 0\}$, confirming the sign. In the Gauss-Green formula, the two minus signs cancel, leaving the classical positive sign $\int_E \operatorname{div} \phi = \int_{\partial^* E} \phi \cdot \nu_E$.[/guided]