[guided]We use [De Giorgi's Structure Theorem](/theorems/599) to express $D\mathbb{1}_E$ in concrete terms, then substitute into the distributional identity from Step 1.
*Polar decomposition of a vector-valued Radon measure.* Any $\mathbb{R}^n$-valued Radon measure $\mu$ on $U$ admits a polar decomposition
\begin{align*}
\mu = \nu_\mu \cdot |\mu|,
\end{align*}
where $|\mu|$ is the total variation (a non-negative Radon measure) and $\nu_\mu = d\mu/d|\mu|: U \to S^{n-1}$ is a Borel-measurable unit vector field, defined $|\mu|$-a.e. by the Radon-Nikodym theorem.
*Hypothesis verification for [De Giorgi's Structure Theorem](/theorems/599).* The theorem requires $E \subseteq \mathbb{R}^n$ to be a Borel-measurable set of finite perimeter. Both hypotheses are explicit: $E$ is given as a Borel set of finite perimeter in $U$. (Technical point: De Giorgi's theorem in [theorem 599](/theorems/599) is stated for sets of finite perimeter in $\mathbb{R}^n$, but the conclusions are local — the polar decomposition holds inside any open set $U$ where $E$ has finite perimeter, by restricting all measures and densities to $U$.)
*Conclusions of De Giorgi.* Part (c) gives $|D\mathbb{1}_E|(A) = \mathcal{H}^{n-1}(A \cap \partial^* E)$ for every Borel $A \subseteq \mathbb{R}^n$, so
\begin{align*}
|D\mathbb{1}_E| = \mathcal{H}^{n-1}\lfloor \partial^* E
\end{align*}
as Borel measures. Part (d) gives the Radon-Nikodym derivative $dD\mathbb{1}_E / d|D\mathbb{1}_E| = -\nu_E$ at $\mathcal{H}^{n-1}$-a.e. $x \in \partial^* E$, where $\nu_E$ is the measure-theoretic outer unit normal. The minus sign records the orientation convention: $\nu_E$ points outward (from $E$ to $E^c$), whereas the gradient measure $D\mathbb{1}_E$ "points" from $E^c$ to $E$ (the direction in which $\mathbb{1}_E$ increases). Combining,
\begin{align*}
D\mathbb{1}_E = (-\nu_E) \cdot (\mathcal{H}^{n-1}\lfloor \partial^* E) = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \partial^* E.
\end{align*}
*Action on $\phi$.* For $\phi \in C_c^1(U; \mathbb{R}^n)$, the action of $D\mathbb{1}_E$ on $\phi$ is the integral
\begin{align*}
\int_U \phi \cdot dD\mathbb{1}_E = \int_U \phi(x) \cdot (-\nu_E(x)) \, d(\mathcal{H}^{n-1}\lfloor \partial^* E)(x) = -\int_{\partial^* E \cap U} \phi(x) \cdot \nu_E(x) \, d\mathcal{H}^{n-1}(x).
\end{align*}
The notation $\mathcal{H}^{n-1}\lfloor \partial^* E$ means the integration is against $\mathcal{H}^{n-1}$ on the set $\partial^* E$; the further restriction to $\partial^* E \cap U$ comes from $\phi$ being supported in $U$. The integrand $\phi \cdot \nu_E$ is well-defined $\mathcal{H}^{n-1}$-a.e. on $\partial^* E$ because $\nu_E$ is defined $\mathcal{H}^{n-1}$-a.e. on $\partial^* E$ as part of the structure theorem.
*Removing the explicit $U$-restriction.* Because $\phi \in C_c^1(U; \mathbb{R}^n)$ has compact support contained in $U$, the integrand $\phi \cdot \nu_E$ vanishes outside the (compact) support of $\phi$, hence in particular vanishes $\mathcal{H}^{n-1}$-a.e. on $\partial^* E \setminus U$. Therefore
\begin{align*}
\int_{\partial^* E \cap U} \phi \cdot \nu_E \, d\mathcal{H}^{n-1} = \int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}.
\end{align*}
*Substitution into Step 1's identity.* From Step 1,
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = -\int_U \phi \cdot dD\mathbb{1}_E.
\end{align*}
Inserting the formula from above:
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = -\Bigl( -\int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1} \Bigr) = \int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}.
\end{align*}
The two minus signs cancel.
*Conclusion.* For every $\phi \in C_c^1(U; \mathbb{R}^n)$,
\begin{align*}
\int_E \operatorname{div} \phi \, d\mathcal{L}^n = \int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1},
\end{align*}
which is the Gauss-Green theorem for sets of finite perimeter. The proof is complete.
*Sign-convention check.* The minus sign in the polar decomposition $D\mathbb{1}_E = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \partial^* E$ is the only delicate point. To verify it on a model example, take $E := \{x_n < 0\}$ in $\mathbb{R}^n$ (so $U = \mathbb{R}^n$). The classical outer normal is $\nu_E = e_n$ (pointing into $\{x_n > 0\}$, away from $E$). For $\phi = (\phi_1, \ldots, \phi_n) \in C_c^1(\mathbb{R}^n; \mathbb{R}^n)$, the distributional gradient acts as
\begin{align*}
D\mathbb{1}_E(\phi) = -\int_E \operatorname{div} \phi \, d\mathcal{L}^n = -\int_{\mathbb{R}^{n-1}} \int_{-\infty}^0 \operatorname{div} \phi(x', x_n) \, d\mathcal{L}^1(x_n) \, d\mathcal{L}^{n-1}(x') = -\int_{\mathbb{R}^{n-1}} \phi_n(x', 0) \, d\mathcal{L}^{n-1}(x'),
\end{align*}
using Fubini and the one-dimensional fundamental theorem of calculus on each fibre (with $\phi_n$ supported in a bounded $x_n$-interval). On the other hand, $\partial^* E = \{x_n = 0\}$ with $\nu_E = e_n$, so
\begin{align*}
\int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1} = \int_{\mathbb{R}^{n-1}} \phi(x', 0) \cdot e_n \, d\mathcal{L}^{n-1}(x') = \int_{\mathbb{R}^{n-1}} \phi_n(x', 0) \, d\mathcal{L}^{n-1}(x').
\end{align*}
Comparing, $D\mathbb{1}_E(\phi) = -\int_{\partial^* E} \phi \cdot \nu_E \, d\mathcal{H}^{n-1}$, confirming the polar decomposition $D\mathbb{1}_E = -\nu_E \cdot \mathcal{H}^{n-1}\lfloor \{x_n = 0\}$. In the Gauss-Green formula the two minus signs cancel, leaving the classical positive sign.[/guided]