[step:Pass to the $L^1$ limit and identify $u$ with $F$ up to a constant]By the standard convergence of mollifications in $L^p$, as $\varepsilon \to 0$,
\begin{align*}
u_\varepsilon \to u \quad \text{in } L^1_{\mathrm{loc}}(\mathbb{R}), \qquad v * \eta_\varepsilon \to v \quad \text{in } L^1_{\mathrm{loc}}(\mathbb{R}).
\end{align*}
In particular, on $[\alpha, \beta]$,
\begin{align*}
\int_\alpha^\beta |u_\varepsilon - u|\, d\mathcal{L}^1 \to 0, \qquad \int_\alpha^\beta |v * \eta_\varepsilon - v|\, d\mathcal{L}^1 \to 0.
\end{align*}
Fix any $y \in (\alpha, \beta)$ and integrate the identity from Step 2 in $x$ over $[\alpha, \beta]$:
\begin{align*}
\int_\alpha^\beta u_\varepsilon(x)\, d\mathcal{L}^1(x) - (\beta - \alpha)\, u_\varepsilon(y) = \int_\alpha^\beta \int_y^x (v * \eta_\varepsilon)(t)\, d\mathcal{L}^1(t)\, d\mathcal{L}^1(x).
\end{align*}
The left-hand side does not directly give the desired identity for $u$; instead we proceed pointwise using the Lebesgue differentiation theorem. Since $u \in L^1(a,b)$ implies $u \in L^1_{\mathrm{loc}}(a,b)$ (any $L^1$ function on a bounded interval is locally integrable), $\mathcal{L}^1$-a.e. point of $(a,b)$ is a Lebesgue point of $u$, and similarly for $v$. The standard mollifier $\eta_\varepsilon$ is non-negative, radial, and supported in $[-\varepsilon,\varepsilon]$ with unit mass, so at every Lebesgue point $x \in (\alpha, \beta)$ of $u$,
\begin{align*}
u_\varepsilon(x) = \int_{\mathbb{R}} u(x - z)\, \eta_\varepsilon(z)\, d\mathcal{L}^1(z) \xrightarrow{\varepsilon \to 0} u(x),
\end{align*}
by mollifier convergence at Lebesgue points (the average of $u$ against the radial weight $\eta_\varepsilon$ on $B(x,\varepsilon)$ converges to $u(x)$), and similarly $(v * \eta_\varepsilon)(x) \to v(x)$ at Lebesgue points of $v$. Moreover, for any $y < x$ in $(\alpha, \beta)$,
\begin{align*}
\int_y^x (v * \eta_\varepsilon)(t)\, d\mathcal{L}^1(t) \xrightarrow{\varepsilon \to 0} \int_y^x v(t)\, d\mathcal{L}^1(t) = F(x) - F(y),
\end{align*}
since $v * \eta_\varepsilon \to v$ in $L^1([\alpha, \beta])$ and integration over $[y, x]$ is a continuous functional on $L^1$.
Take $y \in (\alpha, \beta)$ to be a common Lebesgue point of $u$, and fix it. For every Lebesgue point $x \in (\alpha, \beta)$ of $u$ with $x > y$ (the case $x < y$ is symmetric), Step 2 gives
\begin{align*}
u_\varepsilon(x) - u_\varepsilon(y) = \int_y^x (v * \eta_\varepsilon)(t)\, d\mathcal{L}^1(t).
\end{align*}
Sending $\varepsilon \to 0$,
\begin{align*}
u(x) - u(y) = F(x) - F(y).
\end{align*}
Setting $c := u(y) - F(y)$, this gives $u(x) = F(x) + c$ for $\mathcal{L}^1$-a.e. $x \in (\alpha, \beta)$. Since the Lebesgue points of $u$ have full measure in $(a,b)$ and $[\alpha, \beta] \subset (a,b)$ was arbitrary, $u(x) = F(x) + c$ for $\mathcal{L}^1$-a.e. $x \in (a,b)$. Define $\tilde{u}(x) := F(x) + c$ on $[a,b]$. Then $\tilde{u}$ is absolutely continuous on $[a,b]$ (adding a constant preserves the $\varepsilon$-$\delta$ definition of absolute continuity verbatim, since differences $|\tilde{u}(x_i) - \tilde{u}(y_i)| = |F(x_i) - F(y_i)|$ are unaffected), $\tilde{u}' = F' = v \in L^1(a,b)$ $\mathcal{L}^1$-a.e., and $\tilde{u} = u$ $\mathcal{L}^1$-a.e. on $(a,b)$.[/step]