[step:Identify $T^*$ as the extension operator $\mathcal{E}$ on a dense subspace]
We claim $T^* g = \widehat{g\, d\sigma}$ for $g \in C^\infty(S^{n-1})$, identified with an element of $L^{p'}(\mathbb{R}^n)$.
For $g \in C^\infty(S^{n-1})$, the measure $g\, d\sigma$ is a finite, compactly supported (and in particular tempered) measure on $\mathbb{R}^n$. Its Fourier transform
\begin{align*}
\widehat{g\, d\sigma} : \mathbb{R}^n &\to \mathbb{C} \\
x &\mapsto \int_{S^{n-1}} g(\omega)\, e^{i x \cdot \omega}\, d\sigma(\omega)
\end{align*}
is a smooth bounded function on $\mathbb{R}^n$ (smooth because differentiation under the integral is justified by uniform integrability on the compact set $S^{n-1}$, bounded by $|g|_\infty\, \sigma(S^{n-1}) < \infty$). For $f \in \mathcal{S}(\mathbb{R}^n)$, Fubini's theorem applies (the integrand $g(\omega)\, \overline{f(x)}\, e^{i x \cdot \omega}$ is integrable on $\mathbb{R}^n \times S^{n-1}$ because $f \in L^1(\mathbb{R}^n)$ and $g \in L^\infty(S^{n-1}, d\sigma)$ with $\sigma(S^{n-1}) < \infty$), so
\begin{align*}
(T_0 f, g)_{L^2(d\sigma)} &= \int_{S^{n-1}} \hat f(\omega)\, \overline{g(\omega)}\, d\sigma(\omega) \\
&= \int_{S^{n-1}} \!\left( \int_{\mathbb{R}^n} f(x)\, e^{-i\omega \cdot x}\, d\mathcal{L}^n(x) \right) \overline{g(\omega)}\, d\sigma(\omega) \\
&= \int_{\mathbb{R}^n} f(x)\, \overline{ \int_{S^{n-1}} g(\omega)\, e^{i\omega \cdot x}\, d\sigma(\omega)}\, d\mathcal{L}^n(x) \\
&= \int_{\mathbb{R}^n} f(x)\, \overline{\widehat{g\, d\sigma}(x)}\, d\mathcal{L}^n(x) = \langle f, \widehat{g\, d\sigma} \rangle.
\end{align*}
This identity says exactly $(T_0 f, g)_{L^2(d\sigma)} = \langle f, \widehat{g\, d\sigma} \rangle$ for all $f \in \mathcal{S}(\mathbb{R}^n)$ and all $g \in C^\infty(S^{n-1})$. By the definition of the Hilbert--Banach adjoint, this means $T^* g = \widehat{g\, d\sigma}$ as elements of $(L^p)^* = L^{p'}$, provided we know a priori that $\widehat{g\, d\sigma} \in L^{p'}$.
The boundedness $T^* : L^2(d\sigma) \to L^{p'}$ guarantees that $T^* g \in L^{p'}(\mathbb{R}^n)$ for every $g \in L^2(d\sigma)$, in particular for $g \in C^\infty(S^{n-1}) \subset L^2(d\sigma)$. The Riesz representation of $T^* g$ as a bounded linear functional on $L^p(\mathbb{R}^n)$ via $(T_0 f, g)_{L^2(d\sigma)}$ matches the integral pairing $\langle f, \widehat{g\, d\sigma}\rangle$, and a Riesz representative is unique a.e., so $T^* g = \widehat{g\, d\sigma}$ a.e. on $\mathbb{R}^n$ for every $g \in C^\infty(S^{n-1})$.
[/step]