[guided]We set $F$ to be the collection of all elements of $K$ that are separable over $k$. To show $F$ is a subfield, we need closure under addition, subtraction, multiplication, and division.
The key observation is that if $\alpha, \beta \in F$, then $k(\alpha, \beta)/k$ is separable. Here is why. The element $\alpha$ is separable over $k$, so $k(\alpha)/k$ is a separable extension. Now consider $\beta$: it is separable over $k$, meaning its minimal polynomial $m_\beta = \operatorname{min}(\beta, k) \in k[x]$ has no repeated roots. The minimal polynomial of $\beta$ over the larger field $k(\alpha)$ divides $m_\beta$ in $k(\alpha)[x]$ (by the [Properties of the Minimal Polynomial](/theorems/1250), $\operatorname{min}(\beta, k(\alpha)) \mid m_\beta$). Since $m_\beta$ has no repeated roots, neither does any of its divisors. So $\beta$ is separable over $k(\alpha)$, meaning $k(\alpha, \beta) / k(\alpha)$ is separable.
By the [Multiplicativity of Separable Degree](/theorems/3331), $k(\alpha, \beta) / k$ is separable (since both $k(\alpha)/k$ and $k(\alpha, \beta)/k(\alpha)$ are separable). Every element of $k(\alpha, \beta)$ is therefore separable over $k$. Since $\alpha + \beta$, $\alpha - \beta$, $\alpha \beta$, and $\alpha/\beta$ (for $\beta \ne 0$) all belong to $k(\alpha, \beta)$, they lie in $F$. This shows $F$ is a subfield of $K$ containing $k$.[/guided]