[guided]We now turn to the case $k > n$. The strategy is short and clean: $k$-linearity reduces the value of $\alpha$ on an arbitrary tuple to a sum of values on tuples of basis vectors, and the pigeonhole principle — together with the alternating property — kills every term in that sum.
Fix $\alpha \in \Lambda^k(V^*)$ with $k > n$. We will show that $\alpha$ vanishes on every tuple $(v_1, \dots, v_k) \in V^k$. Expand each argument in the basis $e_1, \dots, e_n$ of $V$: for each $b \in \{1, \dots, k\}$, write
\begin{align*}
v_b &= \sum_{j_b = 1}^{n} c_{j_b,b}\, e_{j_b}, \qquad c_{j_b,b} \in \mathbb{R}.
\end{align*}
Because $\alpha$ is $k$-linear in its arguments, expanding all $k$ slots produces a multi-sum
\begin{align*}
\alpha(v_1, \dots, v_k) &= \sum_{j_1 = 1}^{n} \cdots \sum_{j_k = 1}^{n} c_{j_1, 1} \cdots c_{j_k, k}\, \alpha(e_{j_1}, \dots, e_{j_k}).
\end{align*}
We now show that every coefficient $\alpha(e_{j_1}, \dots, e_{j_k})$ in this sum vanishes. Fix any tuple $(j_1, \dots, j_k) \in \{1, \dots, n\}^k$. Since there are $k$ indices $j_1, \dots, j_k$ drawn from a set of size $n$ and $k > n$, the pigeonhole principle guarantees that at least two of them coincide: there exist $a, a' \in \{1, \dots, k\}$ with $a \ne a'$ and $j_a = j_{a'}$.
Now we invoke the alternating property of $\alpha$ directly: by definition, swapping any two arguments of an alternating form multiplies its value by $-1$. Swap the $a$-th and $a'$-th arguments of $\alpha(e_{j_1}, \dots, e_{j_k})$. On the one hand, the swap multiplies the value by $-1$; on the other hand, since $j_a = j_{a'}$ the same basis vector $e_{j_a} = e_{j_{a'}}$ sits in both positions, so the tuple is unchanged and the value is unchanged. Combining,
\begin{align*}
\alpha(e_{j_1}, \dots, e_{j_k}) &= -\alpha(e_{j_1}, \dots, e_{j_k}),
\end{align*}
which (since we are working over $\mathbb{R}$, where $2 \ne 0$) forces $\alpha(e_{j_1}, \dots, e_{j_k}) = 0$. Every term in the multi-sum is therefore zero, and hence $\alpha(v_1, \dots, v_k) = 0$.
The tuple $(v_1, \dots, v_k) \in V^k$ was arbitrary, so $\alpha$ is the zero $k$-form, and $\alpha \in \Lambda^k(V^*)$ was itself arbitrary, so $\Lambda^k(V^*) = \{0\}$.
This is consistent with the dimension formula $\dim_{\mathbb{R}} \Lambda^k(V^*) = \binom{n}{k}$ under the standard convention $\binom{n}{k} = 0$ for $k > n$: the index set $I_{n,k}$ of strictly increasing $k$-tuples in $\{1, \dots, n\}$ is empty whenever $k > n$, so no coordinate wedges $dx_I$ exist and $\Lambda^k(V^*)$ has empty basis.[/guided]