[step:Identify the coefficients via the duality pairing]We claim that the coefficient $a_I$ in $(\ast)$ is given by
\begin{align*}
a_I(x) = \omega_x\bigl(\partial_{x_{i_1}}|_x, \dots, \partial_{x_{i_k}}|_x\bigr), \quad x \in U,
\end{align*}
for each increasing multi-index $I = (i_1, \dots, i_k)$.
To prove this, recall that for covectors $\alpha_1, \dots, \alpha_k \in T_x^*U$ and tangent vectors $v_1, \dots, v_k \in T_xU$, the wedge product evaluates as
\begin{align*}
(\alpha_1 \wedge \dots \wedge \alpha_k)(v_1, \dots, v_k) = \det\bigl( \alpha_p(v_q) \bigr)_{p,q=1}^k.
\end{align*}
Apply this to $\alpha_p = dx_{j_p}|_x$ and $v_q = \partial_{x_{i_q}}|_x$ for increasing multi-indices $J = (j_1, \dots, j_k)$ and $I = (i_1, \dots, i_k)$. Using $dx_{j_p}|_x(\partial_{x_{i_q}}|_x) = \delta_{j_p, i_q}$:
\begin{align*}
\bigl( dx_{j_1} \wedge \dots \wedge dx_{j_k} \bigr)\bigl( \partial_{x_{i_1}}, \dots, \partial_{x_{i_k}} \bigr)\Big|_x = \det\bigl( \delta_{j_p, i_q} \bigr)_{p,q=1}^k = \delta_{IJ},
\end{align*}
where $\delta_{IJ} = 1$ if $I = J$ and $0$ otherwise. Indeed, if $I \ne J$ then either some $j_p$ does not appear among the $i_q$ (giving a zero row) or some $i_q$ does not appear among the $j_p$ (giving a zero column); if $I = J$ then since both multi-indices are strictly increasing, $j_p = i_p$ for all $p$ and the matrix is the identity.
Evaluating both sides of $(\ast)$ on the tuple $(\partial_{x_{i_1}}|_x, \dots, \partial_{x_{i_k}}|_x)$ gives
\begin{align*}
\omega_x(\partial_{x_{i_1}}|_x, \dots, \partial_{x_{i_k}}|_x) = \sum_J a_J(x)\, \delta_{IJ} = a_I(x),
\end{align*}
as claimed.[/step]