[guided]We need to prove something that is not built directly into the definition of $\mathcal A_{\max}$: two charts in $\mathcal A_{\max}$ are known to be compatible with every chart in $\mathcal A$, but they are not a priori known to be compatible with each other.
Let $(U,\varphi)$ and $(V,\psi)$ be charts in $\mathcal A_{\max}$. Smooth compatibility requires both transition maps to be smooth:
\begin{align*}
\psi \circ \varphi^{-1}: \varphi(U \cap V) \to \psi(U \cap V),
\qquad
\varphi \circ \psi^{-1}: \psi(U \cap V) \to \varphi(U \cap V).
\end{align*}
We prove smoothness of the first map. Fix $p \in U \cap V$. Since $\mathcal A$ is an atlas, it covers $M$, so there exists a chart $(W,\theta) \in \mathcal A$ with $p \in W$. The purpose of this chart is to bridge between $(U,\varphi)$ and $(V,\psi)$ through a chart whose compatibility with both is known.
The set $U \cap V \cap W$ is open in $M$, and $\varphi: U \to \varphi(U)$ is a homeomorphism. Hence $\varphi(U \cap V \cap W)$ is an open neighbourhood of $\varphi(p)$ in $\varphi(U \cap V)$. On this neighbourhood, the transition map factors as
\begin{align*}
\psi \circ \varphi^{-1}
=
(\psi \circ \theta^{-1}) \circ (\theta \circ \varphi^{-1}).
\end{align*}
Now each factor is smooth for a reason encoded in the definition of $\mathcal A_{\max}$. Since $(U,\varphi)$ is compatible with every chart in $\mathcal A$, and $(W,\theta) \in \mathcal A$, the map
\begin{align*}
\theta \circ \varphi^{-1}: \varphi(U \cap W) \to \theta(U \cap W)
\end{align*}
is smooth. Since $(V,\psi)$ is compatible with every chart in $\mathcal A$, and $(W,\theta) \in \mathcal A$, the map
\begin{align*}
\psi \circ \theta^{-1}: \theta(V \cap W) \to \psi(V \cap W)
\end{align*}
is smooth. Therefore their composition is smooth on $\varphi(U \cap V \cap W)$.
Because this construction works around every point $p \in U \cap V$, the map $\psi \circ \varphi^{-1}$ is locally smooth at every point of its domain. Smoothness of maps between open subsets of $\mathbb R^n$ is local, so $\psi \circ \varphi^{-1}$ is smooth on $\varphi(U \cap V)$. Repeating the same argument with $(U,\varphi)$ and $(V,\psi)$ interchanged proves that $\varphi \circ \psi^{-1}$ is smooth on $\psi(U \cap V)$. Hence the two charts are smoothly compatible.[/guided]