[proofplan]
We prove the two constructions are inverse in content. Starting from a natural isomorphism $\Phi:H_A\cong F$, we take the element represented by the identity morphism, namely $u=\Phi_A(\operatorname{id}_A)$, and use naturality to show that every component $\Phi_X$ is the map $f\mapsto F(f)(u)$. Since each $\Phi_X$ is bijective, this gives the required existence and uniqueness. Conversely, starting from such an element $u$, we define $\Phi_X(f)=F(f)(u)$; the universal property gives bijectivity of each component, and functoriality of $F$ gives naturality.
[/proofplan]
[step:Extract the universal element from a natural representation]
Assume first that $\Phi:H_A\cong F$ is a natural isomorphism. For each object $X$ of $\mathcal C$, write
\begin{align*}
\Phi_X:\operatorname{Hom}_{\mathcal C}(X,A)\to F(X)
\end{align*}
for the component of $\Phi$ at $X$. Define
\begin{align*}
u:=\Phi_A(\operatorname{id}_A)\in F(A),
\end{align*}
where $\operatorname{id}_A:A\to A$ is the identity morphism of $A$.
Let $X$ be an object of $\mathcal C$ and let $f:X\to A$ be a morphism. Naturality of $\Phi$ with respect to $f:X\to A$ says that
\begin{align*}
F(f)\circ \Phi_A=\Phi_X\circ H_A(f).
\end{align*}
Evaluating this equality at $\operatorname{id}_A\in \operatorname{Hom}_{\mathcal C}(A,A)$ gives
\begin{align*}
F(f)(u)
&=F(f)(\Phi_A(\operatorname{id}_A)) \\
&=\Phi_X(H_A(f)(\operatorname{id}_A)) \\
&=\Phi_X(\operatorname{id}_A\circ f) \\
&=\Phi_X(f).
\end{align*}
Thus, for every morphism $f:X\to A$,
\begin{align*}
\Phi_X(f)=F(f)(u).
\end{align*}
[/step]
[step:Use bijectivity of the representation to prove the universal property]
Let $X$ be an object of $\mathcal C$ and let $s\in F(X)$. Since $\Phi$ is a natural isomorphism, the component
\begin{align*}
\Phi_X:\operatorname{Hom}_{\mathcal C}(X,A)\to F(X)
\end{align*}
is a bijection. Therefore there exists a unique morphism $f:X\to A$ such that
\begin{align*}
\Phi_X(f)=s.
\end{align*}
By the identity proved in the previous step, $\Phi_X(f)=F(f)(u)$, so this unique morphism is precisely the unique morphism satisfying
\begin{align*}
F(f)(u)=s.
\end{align*}
Hence $u\in F(A)$ has the stated universal property.
[/step]
[step:Construct a natural transformation from a universal element]
Conversely, assume that an element $u\in F(A)$ has the stated universal property. For each object $X$ of $\mathcal C$, define a function
\begin{align*}
\Phi_X:\operatorname{Hom}_{\mathcal C}(X,A)&\to F(X),\\
f&\mapsto F(f)(u).
\end{align*}
This is well-defined because every morphism $f:X\to A$ is sent by the contravariant functor $F$ to a function
\begin{align*}
F(f):F(A)\to F(X),
\end{align*}
so $F(f)(u)$ is an element of $F(X)$.
For each object $X$ of $\mathcal C$, the universal property of $u$ states exactly that for every $s\in F(X)$ there exists a unique $f\in \operatorname{Hom}_{\mathcal C}(X,A)$ with $\Phi_X(f)=s$. Hence each function $\Phi_X$ is bijective.
[/step]
[step:Verify naturality of the constructed bijections]
Let $g:Y\to X$ be a morphism in $\mathcal C$. We must prove that the square
\begin{align*}
F(g)\circ \Phi_X=\Phi_Y\circ H_A(g)
\end{align*}
commutes as functions from $\operatorname{Hom}_{\mathcal C}(X,A)$ to $F(Y)$.
Let $f:X\to A$ be a morphism. By the definition of $\Phi_X$, the definition of $H_A(g)$, and functoriality of the contravariant functor $F:\mathcal C^{\mathrm{op}}\to \mathbf{Set}$, we have
\begin{align*}
(F(g)\circ \Phi_X)(f)
&=F(g)(\Phi_X(f)) \\
&=F(g)(F(f)(u)) \\
&=(F(g)\circ F(f))(u) \\
&=F(f\circ g)(u) \\
&=\Phi_Y(f\circ g) \\
&=\Phi_Y(H_A(g)(f)) \\
&=(\Phi_Y\circ H_A(g))(f).
\end{align*}
Since this equality holds for every $f\in \operatorname{Hom}_{\mathcal C}(X,A)$, the naturality square commutes. Therefore the family $(\Phi_X)_X$ is a natural transformation $\Phi:H_A\to F$.
Each component $\Phi_X$ is bijective by the previous step, so $\Phi$ is a natural isomorphism. This proves that the universal element $u\in F(A)$ determines a representation $H_A\cong F$, completing the equivalence.
[/step]