[guided]The eigenvector statement needs a gap. Since $\lambda_k$ is simple, no other eigenvalue of $\Sigma$ equals $\lambda_k$. We record the smallest separation from $\lambda_k$ to the rest of the spectrum:
\begin{align*}
\delta_k = \min_{j\neq k}|\lambda_j-\lambda_k|.
\end{align*}
This is positive because the set $\{j:j\neq k\}$ is finite and every term in the minimum is positive.
Let
\begin{align*}
E_n=S_n-\Sigma,
\qquad
\eta_n=\|E_n\|_{\mathrm{op}}.
\end{align*}
We work on the event $\eta_n<\delta_k/2$. Weyl's eigenvalue perturbation inequality gives
\begin{align*}
|\hat{\lambda}_{k,n}-\lambda_k|\leq \eta_n<\frac{\delta_k}{2}.
\end{align*}
This says the sample eigenvalue associated to the $k$-th component stays inside the spectral gap around $\lambda_k$.
Now take the signed unit eigenvector $\hat{\gamma}_{k,n}$ from the statement:
\begin{align*}
S_n\hat{\gamma}_{k,n}=\hat{\lambda}_{k,n}\hat{\gamma}_{k,n},
\qquad
|\hat{\gamma}_{k,n}|=1,
\qquad
\hat{\gamma}_{k,n}^\top\gamma_k\geq0.
\end{align*}
Because $\Sigma$ is real symmetric, the spectral theorem gives an orthonormal eigenbasis $\gamma_1,\dots,\gamma_p$ with $\Sigma\gamma_j=\lambda_j\gamma_j$. Decompose $\hat{\gamma}_{k,n}$ into the component in the target eigendirection and the orthogonal remainder:
\begin{align*}
\hat{\gamma}_{k,n}=a_n\gamma_k+w_n,
\end{align*}
where
\begin{align*}
a_n=\hat{\gamma}_{k,n}^\top\gamma_k\in[0,1],
\qquad
w_n\in\operatorname{span}\{\gamma_j:j\neq k\}.
\end{align*}
The sign choice is exactly what guarantees $a_n\geq0$.
The residual of $\hat{\gamma}_{k,n}$ under $\Sigma-\hat{\lambda}_{k,n}I$ is controlled by the perturbation:
\begin{align*}
(\Sigma-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}
&=
(\Sigma-S_n)\hat{\gamma}_{k,n}
+
(S_n-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}\\
&=
-E_n\hat{\gamma}_{k,n},
\end{align*}
because $(S_n-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}=0$. Since $|\hat{\gamma}_{k,n}|=1$,
\begin{align*}
\|(\Sigma-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}\|_{\mathbb{R}^p}
\leq
\|E_n\|_{\mathrm{op}}|\hat{\gamma}_{k,n}|
=
\eta_n.
\end{align*}
Write
\begin{align*}
w_n=\sum_{j\neq k}c_{j,n}\gamma_j.
\end{align*}
Then
\begin{align*}
(\Sigma-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}
=
a_n(\lambda_k-\hat{\lambda}_{k,n})\gamma_k
+
\sum_{j\neq k} c_{j,n}(\lambda_j-\hat{\lambda}_{k,n})\gamma_j.
\end{align*}
For every $j\neq k$, the triangle inequality gives
\begin{align*}
|\lambda_j-\hat{\lambda}_{k,n}|
&\geq
|\lambda_j-\lambda_k|-|\lambda_k-\hat{\lambda}_{k,n}|\\
&\geq
\delta_k-\eta_n\\
&>
\frac{\delta_k}{2}.
\end{align*}
Since the basis is orthonormal, the squared norm is the sum of squared coefficients. Therefore
\begin{align*}
\eta_n^2
&\geq
\|(\Sigma-\hat{\lambda}_{k,n}I)\hat{\gamma}_{k,n}\|_{\mathbb{R}^p}^2\\
&\geq
\sum_{j\neq k}|c_{j,n}|^2|\lambda_j-\hat{\lambda}_{k,n}|^2\\
&\geq
\frac{\delta_k^2}{4}\sum_{j\neq k}|c_{j,n}|^2\\
&=
\frac{\delta_k^2}{4}|w_n|^2.
\end{align*}
Thus
\begin{align*}
|w_n|\leq \frac{2\eta_n}{\delta_k}.
\end{align*}
The meaning of this estimate is that a small perturbation cannot move the eigenvector significantly into the orthogonal spectral subspace when the target eigenvalue is separated from the rest of the spectrum.[/guided]