[guided]Fix an integer $m \geq 1$, an $\mathcal{L}_{\mathrm{or}}$-formula $\varphi(x_1,\dots,x_m)$, and a tuple $a = (a_1,\dots,a_m) \in K^m$. The obstacle is that $\varphi$ may contain quantifiers over the ambient field, so a direct comparison between $K$ and $L$ would have to compare two different domains of quantification.
Quantifier elimination removes that obstacle. By the quantifier elimination theorem for real closed ordered fields (citing a result not yet in the wiki: Quantifier Elimination for Real Closed Fields), there is a quantifier-free $\mathcal{L}_{\mathrm{or}}$-formula $\psi(x_1,\dots,x_m)$ such that every real closed ordered field satisfies
\begin{align*}
\forall x_1 \cdots \forall x_m \, \bigl(\varphi(x_1,\dots,x_m) \leftrightarrow \psi(x_1,\dots,x_m)\bigr).
\end{align*}
Because both $K$ and $L$ are models of $\operatorname{RCF}$, this equivalence is valid inside both structures. Evaluating at the tuple $a \in K^m \subset L^m$ gives
\begin{align*}
K \models \varphi(a_1,\dots,a_m)
&\Longleftrightarrow K \models \psi(a_1,\dots,a_m), \\
L \models \varphi(a_1,\dots,a_m)
&\Longleftrightarrow L \models \psi(a_1,\dots,a_m).
\end{align*}
Therefore the whole problem has been reduced to the following purely algebraic fact: quantifier-free ordered-ring formulas cannot distinguish $K$ from $L$ when all parameters lie in $K$.[/guided]