[step:Use positive definiteness to classify the connected diagrams]
Let $D$ be the diagonal matrix with entries
\begin{align*}
d_i := \frac{(\alpha_i,\alpha_i)_E}{2}\quad \text{for }1\le i\le n.
\end{align*}
Then $G:=AD$ has entries $G_{ij}=(\alpha_i,\alpha_j)_E$, so $G$ is the Gram matrix of the basis $\Delta$. Since the Euclidean inner product on $E$ is positive definite and $\Delta$ is linearly independent, $G$ is positive definite. Hence $A$ is symmetrizable positive definite.
Define the quadratic form attached to the diagram by
\begin{align*}
Q: \mathbb R^n &\to \mathbb R,\\
(x_1,\dots,x_n) &\mapsto \sum_{i,j=1}^n G_{ij}x_i x_j.
\end{align*}
The preceding paragraph proves that $Q(x)>0$ for every non-zero $x\in \mathbb R^n$. The finite Dynkin diagram classification theorem applies to a connected symmetrizable generalized Cartan matrix whose symmetrization is positive definite and whose off-diagonal products satisfy $a_{ij}a_{ji}\in\{0,1,2,3\}$. Its hypotheses are exactly the connectedness from irreducibility, the Cartan-integrality and sign conditions from the simple-root construction, the rank-two restriction from the previous step, and the positive definiteness of $Q$.
The theorem classifies the resulting connected diagrams as precisely
\begin{align*}
A_n\ (n\ge 1),\quad B_n\ (n\ge 2),\quad C_n\ (n\ge 3),\quad D_n\ (n\ge 4),\quad E_6,E_7,E_8,F_4,G_2.
\end{align*}
In the standard proof of this finite-diagram theorem, the same form $Q$ is evaluated on explicit integer vectors supported on forbidden subdiagrams: cycles give a non-zero vector with $Q\le 0$, vertices with excessive branching give a non-zero vector with $Q\le 0$, and the inverse Cartan matrices of the simply-laced arms give the branch-length bound that leaves only $D_n,E_6,E_7,E_8$ beyond the paths $A_n$. The multiply-laced case is then reduced by the rank-two products $1,2,3$ and the positivity of $Q$, leaving only the chains $B_n,C_n$ and the exceptional diagrams $F_4,G_2$. Therefore $\Gamma(\Phi,\Delta)$ is one of the diagrams in the displayed list.
[/step]