[step:Use a complete PA extension to define a binary diagonal avoider]
Assume $a$ is a PA degree. Let $A \in a$ compute a complete consistent extension $T$ of PA, regarded as a set of Gödel codes of arithmetic sentences. Fix a standard primitive recursive computation predicate $C(e,x,b,t)$ with the meaning that the computation of $\varphi_e(x)$ halts by stage $t$ with value $b \in \{0,1\}$. We use the standard formalisation for which PA proves uniqueness of computation values: for all $e,x,t,s \in \mathbb{N}$, PA proves that $C(e,x,0,t)$ and $C(e,x,1,s)$ cannot both hold.
For each $e \in \mathbb{N}$, let $\alpha_e$ be the arithmetic sentence
\begin{align*}
\neg \exists t \, C(e,e,1,t).
\end{align*}
The map $e \mapsto \ulcorner \alpha_e \urcorner$ is computable. Define
\begin{align*}
f: \mathbb{N} &\to \{0,1\} \\
e &\mapsto
\begin{cases}
1, & \text{if } \ulcorner \alpha_e \urcorner \in T,\\
0, & \text{if } \ulcorner \neg \alpha_e \urcorner \in T.
\end{cases}
\end{align*}
Since $T$ is complete and consistent, exactly one of $\alpha_e$ and $\neg \alpha_e$ belongs to $T$, so $f$ is a total $\{0,1\}$-valued function. Since $A$ computes $T$ and $e \mapsto \ulcorner \alpha_e \urcorner$ is computable, $A$ computes $f$.
It remains to verify diagonal disagreement. Let $e \in \mathbb{N}$.
If $\varphi_e(e)=1$, then for some $t \in \mathbb{N}$ the true primitive recursive fact $C(e,e,1,t)$ holds. PA proves each true instance of a primitive recursive computation fact, so PA proves $\exists t\, C(e,e,1,t)$, hence PA proves $\neg \alpha_e$. Since $T$ extends PA and is consistent, $\alpha_e \notin T$, so $f(e)=0 \neq 1$.
If $\varphi_e(e)=0$, then for some $t \in \mathbb{N}$ the true primitive recursive fact $C(e,e,0,t)$ holds. By PA-verifiable uniqueness of computation values, PA proves
\begin{align*}
C(e,e,0,t) \implies \neg \exists s\, C(e,e,1,s).
\end{align*}
Thus PA proves $\alpha_e$. Since $T$ extends PA, $\alpha_e \in T$, and therefore $f(e)=1 \neq 0$.
Thus $f$ is diagonally noncomputable relative to $(\varphi_e)_{e \in \mathbb{N}}$.
[/step]