[guided]The purpose of this step is to isolate the term whose distribution we can compute exactly. Define
\begin{align*}
v_{n,j} := \hat\theta_{n,j}^\top\hat\Sigma_n\hat\theta_{n,j}.
\end{align*}
The theorem assumes $c \le v_{n,j} \le C$, so the normalising denominator
\begin{align*}
\sigma(v_{n,j}/n)^{1/2}
\end{align*}
is positive and finite.
Now define the leading coordinate score
\begin{align*}
G_{n,j} :=
\hat\theta_{n,j}^\top\frac{X_n^\top\varepsilon_n}{n}.
\end{align*}
This is a linear functional of the Gaussian vector $\varepsilon_n$. Because $X_n$ is fixed and $\hat\theta_{n,j}$ is constructed only from $X_n$, the vector $X_n\hat\theta_{n,j}/n \in \mathbb{R}^n$ is deterministic. Hence $G_{n,j}$ is a centered Gaussian scalar. Its variance is computed directly from $\operatorname{Var}(\varepsilon_n)=\sigma^2 I_n$. First,
\begin{align*}
\operatorname{Var}(G_{n,j}) = \operatorname{Var}\left(\frac{1}{n}\hat\theta_{n,j}^\top X_n^\top\varepsilon_n\right).
\end{align*}
The covariance formula for a deterministic linear functional gives
\begin{align*}
\operatorname{Var}(G_{n,j}) = \frac{1}{n^2}\hat\theta_{n,j}^\top X_n^\top \operatorname{Var}(\varepsilon_n) X_n\hat\theta_{n,j}.
\end{align*}
Substituting $\operatorname{Var}(\varepsilon_n)=\sigma^2 I_n$, we obtain
\begin{align*}
\operatorname{Var}(G_{n,j}) = \frac{\sigma^2}{n^2}\hat\theta_{n,j}^\top X_n^\top X_n\hat\theta_{n,j}.
\end{align*}
Because $\hat\Sigma_n=X_n^\top X_n/n$, this is
\begin{align*}
\operatorname{Var}(G_{n,j}) = \frac{\sigma^2}{n}\hat\theta_{n,j}^\top\hat\Sigma_n\hat\theta_{n,j}.
\end{align*}
Finally, the definition $v_{n,j}=\hat\theta_{n,j}^\top\hat\Sigma_n\hat\theta_{n,j}$ gives
\begin{align*}
\operatorname{Var}(G_{n,j}) = \frac{\sigma^2 v_{n,j}}{n}.
\end{align*}
Thus the denominator in the theorem is exactly the standard deviation of $G_{n,j}$. After division by that standard deviation, we obtain
\begin{align*}
Z_{n,j}
:=
\frac{G_{n,j}}{\sigma(v_{n,j}/n)^{1/2}}
\sim \mathcal{N}(0,1).
\end{align*}
This exact normality is the reason the proof reduces to showing that the debiasing remainder is negligible.[/guided]