[guided]We now prove the single-edge inequality in a way that isolates exactly where submodularity comes from. Fix an edge $e=\{u,v\}\in E$. Define $P:=A\setminus B$, $Q:=B\setminus A$, $R:=A\cap B$, and $T:=V\setminus(A\cup B)$. The sets $P,Q,R,T$ are pairwise disjoint and their union is $V$, so each endpoint of $e$ lies in exactly one of these four regions.
The indicator $\kappa_e(S)$ records whether $S$ separates the two endpoints of $e$. Thus, to compute the four quantities
\begin{align*}
\kappa_e(A),\qquad \kappa_e(B),\qquad \kappa_e(A\cup B),\qquad \kappa_e(A\cap B),
\end{align*}
we only need to know the two regions containing $u$ and $v$.
If both endpoints lie in the same region among $P,Q,R,T$, then no set built from membership in $A$ and $B$ separates them. In that case
\begin{align*}
\kappa_e(A)=\kappa_e(B)=\kappa_e(A\cup B)=\kappa_e(A\cap B)=0,
\end{align*}
and the desired inequality holds with equality.
Now suppose the endpoints lie in two distinct regions. Since the edge is unordered, there are six cases. We compute each one.
If the endpoint regions are $P$ and $Q$, then one endpoint lies in $A\setminus B$ and the other lies in $B\setminus A$. The set $A$ separates them, and the set $B$ also separates them. However, both endpoints lie in $A\cup B$, and neither endpoint lies in $A\cap B$. Hence
\begin{align*}
\kappa_e(A)+\kappa_e(B)=2,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=0.
\end{align*}
If the endpoint regions are $P$ and $R$, then both endpoints lie in $A$, but exactly one lies in $B$. Also both endpoints lie in $A\cup B$, while exactly one lies in $A\cap B$. Hence
\begin{align*}
\kappa_e(A)+\kappa_e(B)=0+1=1,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=0+1=1.
\end{align*}
If the endpoint regions are $P$ and $T$, then exactly one endpoint lies in $A$, no endpoint lies in $B$, exactly one endpoint lies in $A\cup B$, and no endpoint lies in $A\cap B$. Hence
\begin{align*}
\kappa_e(A)+\kappa_e(B)=1+0=1,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=1+0=1.
\end{align*}
If the endpoint regions are $Q$ and $R$, the same computation with $A$ and $B$ interchanged gives
\begin{align*}
\kappa_e(A)+\kappa_e(B)=1+0=1,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=0+1=1.
\end{align*}
If the endpoint regions are $Q$ and $T$, then $B$ separates the endpoints, $A$ does not separate them, $A\cup B$ separates them, and $A\cap B$ does not separate them. Therefore
\begin{align*}
\kappa_e(A)+\kappa_e(B)=0+1=1,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=1+0=1.
\end{align*}
Finally, if the endpoint regions are $R$ and $T$, then one endpoint lies in both $A$ and $B$, while the other lies in neither. Therefore both $A$ and $B$ separate the endpoints, and both $A\cup B$ and $A\cap B$ separate the endpoints:
\begin{align*}
\kappa_e(A)+\kappa_e(B)=1+1=2,
\qquad
\kappa_e(A\cup B)+\kappa_e(A\cap B)=1+1=2.
\end{align*}
Every possible placement of the two endpoints has now been covered. In each case,
\begin{align*}
\kappa_e(A)+\kappa_e(B)\geq \kappa_e(A\cup B)+\kappa_e(A\cap B).
\end{align*}[/guided]