[guided]The second moment assumption should be interpreted as saying that the likelihood ratio $L_n$ is close to the constant function $1$ in $L^2(P_n)$. Since total variation is controlled by $L^1(P_n)$ distance of likelihood ratios, the goal is to pass from $L^2$ closeness to $L^1$ closeness.
For each $n \in \mathbb N$, define
\begin{align*}
d_{\mathrm{TV}}(P_n,Q_n)
:=
\sup_{A \in \mathcal A_n}|P_n(A)-Q_n(A)|.
\end{align*}
Because $Q_n \ll P_n$ and $L_n=dQ_n/dP_n$, every measurable set $A \in \mathcal A_n$ satisfies
\begin{align*}
Q_n(A)
=
\int_A L_n(x)\,dP_n(x).
\end{align*}
Subtracting $P_n(A)=\int_A 1\,dP_n(x)$ gives
\begin{align*}
Q_n(A)-P_n(A)
=
\int_A (L_n(x)-1)\,dP_n(x).
\end{align*}
Taking absolute values and enlarging the domain of integration from $A$ to $\mathcal X_n$ gives
\begin{align*}
|Q_n(A)-P_n(A)|
\leq
\int_A |L_n(x)-1|\,dP_n(x).
\end{align*}
Since $A \subset \mathcal X_n$, enlarging the domain of integration gives
\begin{align*}
\int_A |L_n(x)-1|\,dP_n(x)
\leq
\int_{\mathcal X_n}|L_n(x)-1|\,dP_n(x).
\end{align*}
Since this holds for every $A \in \mathcal A_n$, taking the supremum over $A$ yields
\begin{align*}
d_{\mathrm{TV}}(P_n,Q_n)
\leq
\int_{\mathcal X_n}|L_n(x)-1|\,dP_n(x).
\end{align*}
Now we convert the $L^1(P_n)$ bound to an $L^2(P_n)$ bound. Apply the Cauchy--Schwarz inequality in the [Hilbert space](/page/Hilbert%20Space) $L^2(\mathcal X_n,\mathcal A_n,P_n)$ to the two functions $|L_n-1|$ and $1$. Since $P_n$ is a probability measure,
\begin{align*}
\int_{\mathcal X_n}1^2\,dP_n(x)=1.
\end{align*}
Thus
\begin{align*}
\int_{\mathcal X_n}|L_n(x)-1|\,dP_n(x)
\leq
\left(\int_{\mathcal X_n}(L_n(x)-1)^2\,dP_n(x)\right)^{1/2}
\left(\int_{\mathcal X_n}1^2\,dP_n(x)\right)^{1/2}.
\end{align*}
Since $\int_{\mathcal X_n}1^2\,dP_n(x)=1$, this yields
\begin{align*}
\int_{\mathcal X_n}|L_n(x)-1|\,dP_n(x)
\leq
\left(\int_{\mathcal X_n}(L_n(x)-1)^2\,dP_n(x)\right)^{1/2}.
\end{align*}
It remains to compute the last integral from the second moment. Since $L_n=dQ_n/dP_n$ and $Q_n$ is a probability measure,
\begin{align*}
\int_{\mathcal X_n}L_n(x)\,dP_n(x)
=
Q_n(\mathcal X_n)
=
1.
\end{align*}
Expanding the square gives
\begin{align*}
\int_{\mathcal X_n}(L_n(x)-1)^2\,dP_n(x)
=
\int_{\mathcal X_n}L_n(x)^2\,dP_n(x)
-2\int_{\mathcal X_n}L_n(x)\,dP_n(x)
+\int_{\mathcal X_n}1\,dP_n(x).
\end{align*}
Substituting $\int_{\mathcal X_n}L_n(x)\,dP_n(x)=1$ and $\int_{\mathcal X_n}1\,dP_n(x)=1$, we obtain
\begin{align*}
\int_{\mathcal X_n}(L_n(x)-1)^2\,dP_n(x)
=
\mathbb E_{P_n}[L_n^2]-1.
\end{align*}
Combining the preceding estimates,
\begin{align*}
d_{\mathrm{TV}}(P_n,Q_n)
\leq
\left(\mathbb E_{P_n}[L_n^2]-1\right)^{1/2}.
\end{align*}
The hypothesis $\mathbb E_{P_n}[L_n^2]\to 1$ therefore implies
\begin{align*}
d_{\mathrm{TV}}(P_n,Q_n)\to 0.
\end{align*}[/guided]