[guided]We need the quotient construction to be meaningful, so the first point is to check that the proposed identification is actually an equivalence relation. Let $X:=\bigsqcup_{i \in I} U_i \times F'$, and write points in $X$ as triples $(i,b,y)$, where $b \in U_i$ and $y \in F'$. The relation says that two representatives over the same base point are identified by the transition diffeomorphism: $(i,b,y)\sim(j,b,z)$ exactly when $z=\gamma_{ji}(b)(y)$. Here $e_G \in G$ denotes the identity element of $G$, and $\operatorname{id}_{F'}:F'\to F'$ denotes the identity diffeomorphism of $F'$.
Reflexivity asks whether $(i,b,y)$ is identified with itself. Since the cocycle satisfies $g_{ii}(b)=e_G$, we have $\gamma_{ii}(b)=\rho(e_G)=\operatorname{id}_{F'}$. Therefore $\gamma_{ii}(b)(y)=y$, so $(i,b,y)\sim(i,b,y)$.
For symmetry, assume $(i,b,y)\sim(j,b,z)$. By definition, $z=\gamma_{ji}(b)(y)$. The cocycle identity gives $\gamma_{ij}(b)\gamma_{ji}(b)=\gamma_{ii}(b)=\operatorname{id}_{F'}$. Applying this identity to $y$ yields
\begin{align*}
\gamma_{ij}(b)(z)=\gamma_{ij}(b)\gamma_{ji}(b)(y)=y.
\end{align*}
Thus $(j,b,z)\sim(i,b,y)$.
For transitivity, assume $(i,b,y)\sim(j,b,z)$ and $(j,b,z)\sim(k,b,w)$. Then $z=\gamma_{ji}(b)(y)$ and $w=\gamma_{kj}(b)(z)$. Substituting the first equation into the second gives $w=\gamma_{kj}(b)\gamma_{ji}(b)(y)$. The cocycle identity with indices $k,j,i$ says $\gamma_{kj}(b)\gamma_{ji}(b)=\gamma_{ki}(b)$, so $w=\gamma_{ki}(b)(y)$. This is precisely the condition $(i,b,y)\sim(k,b,w)$. Hence $\sim$ is an equivalence relation.[/guided]