[guided]The weak formulation contains exactly the spacetime pairing of the flux with the spacetime gradient of the test function. To make this explicit, define
\begin{align*}
F: Q\setminus \Sigma \to \mathbb{R}^{n+1}, \qquad F(t,x):=(u(t,x),f(u(t,x))).
\end{align*}
Then
\begin{align*}
F\cdot \nabla_{t,x}\varphi
=
u\,\partial_t\varphi+f(u)\cdot \nabla_x\varphi.
\end{align*}
Fix $\varphi \in C_c^1(V)$. Since $u$ is a weak solution and $\varphi$ is supported in $V$, we have
\begin{align*}
0
=
\int_{V_-} F\cdot \nabla_{t,x}\varphi\,d\mathcal{L}^{n+1}(t,x)
+
\int_{V_+} F\cdot \nabla_{t,x}\varphi\,d\mathcal{L}^{n+1}(t,x).
\end{align*}
The hypersurface itself does not contribute to this volume integral because a smooth hypersurface has zero $(n+1)$-dimensional [Lebesgue measure](/page/Lebesgue%20Measure).
Now use the classical equation on each side. Since $u$ is $C^1$ on $V_\pm$ up to the interface from the corresponding side and $f \in C^1(\mathbb{R};\mathbb{R}^n)$, the map $F$ is $C^1$ on each side. The chain rule gives
\begin{align*}
\operatorname{div}_{t,x}F
=
\partial_tu+\operatorname{div}_x f(u)
=
0
\end{align*}
on $V_\pm$. Therefore the product rule gives
\begin{align*}
\operatorname{div}_{t,x}(\varphi F)
=
F\cdot \nabla_{t,x}\varphi+\varphi\,\operatorname{div}_{t,x}F
=
F\cdot \nabla_{t,x}\varphi.
\end{align*}
We apply the [Gauss-Green Theorem](/theorems/28) separately on truncated one-sided domains. Let $K:=\operatorname{supp}\varphi$, and choose a smooth open set $V'\Subset V$ with $K\subset V'$. The theorem applies on smooth subdomains lying inside $V'\cap V_-$ and $V'\cap V_+$ because $F$ is $C^1$ in the interior of each side. Letting those subdomains exhaust the two sides gives the boundary terms on $\Sigma$ with the one-sided traces, since $u_\pm$ are the one-sided traces of $u$ and $f\in C^1(\mathbb{R};\mathbb{R}^n)$. Define
\begin{align*}
F_-:\Sigma\cap V \to \mathbb{R}^{n+1}, \qquad F_-(t,x):=(u_-(t,x),f(u_-(t,x)))
\end{align*}
and
\begin{align*}
F_+:\Sigma\cap V \to \mathbb{R}^{n+1}, \qquad F_+(t,x):=(u_+(t,x),f(u_+(t,x))).
\end{align*}
The boundary portions lying in $\partial V'$ give no contribution because $\varphi=0$ there. Along $\Sigma$, the outward unit normal of $V_-$ is $\nu$ because $\nu$ is oriented from the minus side to the plus side. The outward unit normal of $V_+$ is therefore $-\nu$. Hence the two integrations by parts give
\begin{align*}
\int_{V_-} F\cdot \nabla_{t,x}\varphi\,d\mathcal{L}^{n+1}(t,x)
=
\int_{\Sigma\cap V} \varphi\,F_-\cdot \nu\,d\mathcal{H}^{n}(t,x),
\end{align*}
and
\begin{align*}
\int_{V_+} F\cdot \nabla_{t,x}\varphi\,d\mathcal{L}^{n+1}(t,x)
=
-\int_{\Sigma\cap V} \varphi\,F_+\cdot \nu\,d\mathcal{H}^{n}(t,x).
\end{align*}
Adding these identities and using the weak formulation yields
\begin{align*}
0
=
\int_{\Sigma\cap V} \varphi\,F_-\cdot \nu\,d\mathcal{H}^{n}(t,x)
-
\int_{\Sigma\cap V} \varphi\,F_+\cdot \nu\,d\mathcal{H}^{n}(t,x).
\end{align*}
Equivalently,
\begin{align*}
\int_{\Sigma\cap V} \varphi\,\bigl(F_+-F_-\bigr)\cdot \nu\,d\mathcal{H}^{n}(t,x)=0.
\end{align*}
This identity says that every possible trace of a test function on the interface is orthogonal, in the integral sense, to the scalar jump coefficient $(F_+-F_-)\cdot \nu$.[/guided]