[guided]The goal is to put the empirical-process vector into the exact form required by the multivariate [central limit theorem](/theorems/521): a normalized sum of independent identically distributed centred random vectors. The theorem statement supplies the measurable space $(S,\mathcal A)$, the probability measure $P$, and the ambient probability space $(\Omega,\mathcal F,\mathbb P)$. Let $\mathcal B(\mathbb R)$ denote the Borel $\sigma$-algebra on $\mathbb R$, and let $\mathcal B(\mathbb R^k)$ denote the Borel $\sigma$-algebra on $\mathbb R^k$. For any integrable real-valued random variable $H:(\Omega,\mathcal F)\to(\mathbb R,\mathcal B(\mathbb R))$, write $\mathbb E[H]:=\int_\Omega H(\omega)\,d\mathbb P(\omega)$. Thus every occurrence of $\mathbb E[H]$ below is integration with respect to $\mathbb P$, while every expression of the form $P f$ means integration over $S$ with respect to $P$.
Before subtracting $P f_j$, we verify that this number is finite. For each $j\in\{1,\dots,k\}$, the assumption $P f_j^2<\infty$ means
\begin{align*}
\int_S f_j(x)^2\,dP(x)<\infty.
\end{align*}
Since $|a|\le 1+a^2$ for every $a\in\mathbb R$ and $P(S)=1$, we have
\begin{align*}
\int_S |f_j(x)|\,dP(x)\le \int_S \bigl(1+f_j(x)^2\bigr)\,dP(x)<\infty.
\end{align*}
Therefore $P f_j=\int_S f_j(x)\,dP(x)$ is finite.
For each $m \in \mathbb N$, define $Y_m:(\Omega,\mathcal F)\to(\mathbb R^k,\mathcal B(\mathbb R^k))$ by $Y_m(\omega)=\bigl(f_1(X_m(\omega))-P f_1,\dots,f_k(X_m(\omega))-P f_k\bigr)$. This definition subtracts the population mean from each coordinate. Since $X_m:(\Omega,\mathcal F)\to(S,\mathcal A)$ is measurable and each $f_j:(S,\mathcal A)\to(\mathbb R,\mathcal B(\mathbb R))$ is measurable, the composition $f_j\circ X_m:\Omega\to\mathbb R$ is measurable. Hence every coordinate of $Y_m$ is measurable, and therefore $Y_m$ is a Borel-measurable $\mathbb R^k$-valued random vector.
Because $X_1,X_2,\dots$ are independent and identically distributed with law $P$, applying the same measurable map $x\mapsto\bigl(f_1(x)-P f_1,\dots,f_k(x)-P f_k\bigr)$ to each $X_m$ preserves independence and identical distribution. Thus $Y_1,Y_2,\dots$ are independent and identically distributed.
The centering is exact. If $Y_{m,j}:\Omega\to\mathbb R$ denotes the $j$-th coordinate of $Y_m$, then the law of $X_m$ is $P$, so
\begin{align*}
\mathbb E[Y_{m,j}]=\int_\Omega \bigl(f_j(X_m(\omega))-P f_j\bigr)\,d\mathbb P(\omega)=\int_S f_j(x)\,dP(x)-P f_j=0.
\end{align*}
Now compute the normalized sum coordinate by coordinate:
\begin{align*}
\frac{1}{\sqrt n}\sum_{m=1}^n Y_m=\left(\sqrt n\left(\frac{1}{n}\sum_{m=1}^n f_1(X_m)-P f_1\right),\dots,\sqrt n\left(\frac{1}{n}\sum_{m=1}^n f_k(X_m)-P f_k\right)\right)=(\alpha_n(f_1),\dots,\alpha_n(f_k)).
\end{align*}
This identity is the bridge from empirical-process notation to the finite-dimensional [central limit theorem](/theorems/1848).[/guided]