[guided]The Hurwitz hypothesis says that all eigenvalues lie strictly in the open left half-plane. Because there are only finitely many eigenvalues, we can choose $\alpha > 0$ so that every eigenvalue satisfies $\operatorname{Re}(\lambda) \leq -2\alpha$. The extra factor of $2$ gives room to absorb the polynomial growth coming from nontrivial Jordan blocks.
We now regard the real matrix $A$ as the complex-linear map $A_{\mathbb{C}}: \mathbb{C}^n \to \mathbb{C}^n$ with the same matrix entries. This is the correct setting for Jordan form, because the theorem is stated over an algebraically closed field. By the [Canonical Form Over Algebraically Closed Fields](/theorems/428), applied over $\mathbb{C}$ to $A_{\mathbb{C}}$, choose an invertible complex matrix $S \in GL(n,\mathbb{C})$ such that
\begin{align*}
A_{\mathbb{C}} = S J S^{-1},
\end{align*}
where $J$ is block diagonal with Jordan blocks $J_k = \lambda_k I_{m_k} + N_k$. Here $\lambda_k$ is an eigenvalue of $A$, $I_{m_k}$ is the identity matrix in $\mathbb{C}^{m_k \times m_k}$, and $N_k$ is nilpotent with $N_k^{m_k} = 0$.
For $t \geq 0$, the exponential of one block is
\begin{align*}
e^{tJ_k} = e^{t(\lambda_k I_{m_k} + N_k)} = e^{t\lambda_k} e^{tN_k}.
\end{align*}
Since $N_k^{m_k} = 0$, the nilpotent exponential is a finite sum:
\begin{align*}
e^{tN_k} = \sum_{j=0}^{m_k-1} \frac{t^j N_k^j}{j!}.
\end{align*}
Thus
\begin{align*}
e^{tJ_k} = e^{t\lambda_k} \sum_{j=0}^{m_k-1} \frac{t^j N_k^j}{j!}.
\end{align*}
The scalar factor satisfies $|e^{t\lambda_k}| = e^{t\operatorname{Re}(\lambda_k)} \leq e^{-2\alpha t}$. The finite nilpotent sum is bounded in operator norm by a polynomial $p_k: [0,\infty)\to[0,\infty)$. We use the elementary exponential domination lemma for polynomials: for every polynomial $p_0: [0,\infty) \to [0,\infty)$ and every $\beta>0$, there is a constant $C(p_0,\beta)>0$ such that $p_0(t)\leq C(p_0,\beta)e^{\beta t}$ for all $t\geq 0$. Applying this with $p_0=p_k$ and $\beta=\alpha$, there exists $C_k > 0$ such that
\begin{align*}
\|e^{tJ_k}\|_{\mathrm{op}} \leq C_k e^{-\alpha t}
\end{align*}
for every $t \geq 0$.
Since $J$ is block diagonal, $e^{tJ}$ is block diagonal with blocks $e^{tJ_k}$. Let $B_J \geq 1$ denote the finite-dimensional constant comparing the operator norm of a block diagonal matrix with the maximum of its block operator norms, so
\begin{align*}
\|e^{tJ}\|_{\mathrm{op}} \leq B_J \max_k \|e^{tJ_k}\|_{\mathrm{op}}.
\end{align*}
Finally,
\begin{align*}
e^{tA_{\mathbb{C}}} = S e^{tJ} S^{-1}.
\end{align*}
Taking operator norms and defining
\begin{align*}
C_A := \|S\|_{\mathrm{op}} \|S^{-1}\|_{\mathrm{op}} B_J \max_k C_k,
\end{align*}
gives
\begin{align*}
\|e^{tA_{\mathbb{C}}}\|_{\mathrm{op}} \leq C_A e^{-\alpha t}.
\end{align*}
Because $e^{tA_{\mathbb{C}}}$ restricts to $e^{tA}$ on $\mathbb{R}^n \subset \mathbb{C}^n$, the same estimate holds for the real matrix exponential. This is the exact decay estimate needed to make the Lyapunov integral converge.[/guided]