[step:Identify positive definiteness with observability]
Let $\mathcal{O}: \mathbb{R}^n \to \mathbb{R}^{mn}$ be the observability map defined by
\begin{align*}
\mathcal{O}(x) := (Cx, CAx, \dots, CA^{n-1}x) \quad \text{for } x \in \mathbb{R}^n,
\end{align*}
where the tuple is identified with an element of $\mathbb{R}^{mn}$ by stacking its $n$ components in order. By the finite-dimensional definition of observability, the pair $(C,A)$ is observable exactly when $\ker \mathcal{O}=\{0\}$.
Assume first that $(C,A)$ is not observable. Then there exists $x \in \mathbb{R}^n$ with $x \neq 0$ and
\begin{align*}
CA^k x=0
\end{align*}
for every $k \in \{0,\dots,n-1\}$. By the [Cayley-Hamilton Theorem](/theorems/586), every power $A^k$ with $k \geq n$ is a linear combination of $I,A,\dots,A^{n-1}$, so $CA^k x=0$ for every $k \geq 0$. Expanding the matrix exponential in its absolutely convergent [power series](/page/Power%20Series) gives
\begin{align*}
Ce^{tA}x = \sum_{k=0}^\infty \frac{t^k}{k!}CA^k x = 0
\end{align*}
for every $t \geq 0$. Therefore
\begin{align*}
x^\top W_o x = \int_0^\infty |Ce^{tA}x|^2\, d\mathcal{L}^1(t)=0.
\end{align*}
Since $x \neq 0$, $W_o$ is not positive definite.
Conversely, assume $W_o$ is not positive definite. Since $W_o$ is positive semidefinite, there exists $x \in \mathbb{R}^n$ with $x \neq 0$ and $x^\top W_o x=0$. Hence
\begin{align*}
\int_0^\infty |Ce^{tA}x|^2\, d\mathcal{L}^1(t)=0.
\end{align*}
The function $t \mapsto |Ce^{tA}x|^2$ is continuous and nonnegative, so it must vanish for every $t \geq 0$: if it were positive at some $t_0 \geq 0$, continuity would give a neighbourhood of $t_0$ on which it is bounded below by a positive constant, and that neighbourhood has positive $\mathcal{L}^1$-measure in $[0,\infty)$. Thus $Ce^{tA}x=0$ for every $t \geq 0$. Differentiating the map $t \mapsto Ce^{tA}x$ at $t=0$ repeatedly gives
\begin{align*}
CA^k x=0
\end{align*}
for every $k \in \{0,\dots,n-1\}$. Hence $x \in \ker \mathcal{O}$ and $x \neq 0$, so $(C,A)$ is not observable.
We have proved that $(C,A)$ fails to be observable exactly when $W_o$ fails to be positive definite. Equivalently, $(C,A)$ is observable if and only if $W_o$ is positive definite.
[/step]