[step:Split relative entropy into Lebesgue entropy and potential energy]
For any $\nu \in \mathcal P_2(\mathbb R^n)$ with $H(\nu\mid\mu)<\infty$, write $\nu=\rho_\nu \mathcal L^n$, where $\rho_\nu:\mathbb R^n\to[0,\infty)$ is the Lebesgue density of $\nu$. Define the Lebesgue entropy functional $E_{\mathcal L}:\mathcal P_2(\mathbb R^n)\to(-\infty,\infty]$ by
\begin{align*}
E_{\mathcal L}(\nu):=\int_{\mathbb R^n}\rho_\nu(x)\log \rho_\nu(x)\, d\mathcal L^n(x)
\end{align*}
when $\nu=\rho_\nu\mathcal L^n$, and $E_{\mathcal L}(\nu):=+\infty$ otherwise. Define the potential energy functional $P_V:\mathcal P_2(\mathbb R^n)\to(-\infty,\infty]$ by
\begin{align*}
P_V(\nu):=\int_{\mathbb R^n}V(x)\, d\nu(x).
\end{align*}
Define the reference density $p:\mathbb R^n\to(0,\infty)$ by
\begin{align*}
p(x):=Z^{-1}e^{-V(x)}.
\end{align*}
Then $\mu=p\mathcal L^n$. Define the Radon-Nikodym derivative as the measurable map
\begin{align*}
r_\nu:\mathbb R^n\to[0,\infty]
\end{align*}
given $\mu$-a.e. by
\begin{align*}
r_\nu=\frac{d\nu}{d\mu}.
\end{align*}
Since $\nu=\rho_\nu\mathcal L^n$, this derivative satisfies
\begin{align*}
r_\nu(x)=\frac{\rho_\nu(x)}{p(x)}=Z e^{V(x)}\rho_\nu(x)
\end{align*}
for $\nu$-a.e. $x$. The change of reference measure in the definition of relative entropy gives
\begin{align*}
H(\nu\mid\mu)=\int_{\mathbb R^n}\rho_\nu(x)\log\frac{\rho_\nu(x)}{p(x)}\, d\mathcal L^n(x)
\end{align*}
as an extended integral, with the convention $0\log 0=0$. On the set where $\rho_\nu>0$, we have
\begin{align*}
\log\frac{\rho_\nu(x)}{p(x)}=\log\rho_\nu(x)+V(x)+\log Z.
\end{align*}
The set where $\rho_\nu=0$ contributes zero to the density-weighted integrals. Therefore, whenever $E_{\mathcal L}(\nu)$ and $P_V(\nu)$ are not combined in the indeterminate form $\infty-\infty$, the definition of the signed [Lebesgue integral](/page/Lebesgue%20Integral) gives
\begin{align*}
H(\nu\mid\mu)=E_{\mathcal L}(\nu)+P_V(\nu)+\log Z.
\end{align*}
For the endpoint measures, the next paragraph proves that $E_{\mathcal L}(\nu_i)$ and $P_V(\nu_i)$ are finite [real numbers](/page/Real%20Numbers), so the displayed identity is then an ordinary equality for $i\in\{0,1\}$.
The terms in this identity are finite for $\nu_0$ and $\nu_1$. Indeed, Taylor's formula with integral remainder and the Hessian lower bound give
\begin{align*}
V(x)\ge V(0)+\nabla V(0)\cdot x+\frac{\rho}{2}|x|^2.
\end{align*}
[Young's inequality](/theorems/244) applied to the Euclidean [inner product](/page/Inner%20Product) $\nabla V(0)\cdot x$ gives
\begin{align*}
\nabla V(0)\cdot x\ge -\frac{\rho}{4}|x|^2-\frac{|\nabla V(0)|^2}{\rho},
\end{align*}
so define the constant
\begin{align*}
m:=V(0)-\frac{|\nabla V(0)|^2}{\rho}.
\end{align*}
Then
\begin{align*}
V(x)\ge \frac{\rho}{4}|x|^2+m
\end{align*}
for every $x\in\mathbb R^n$. For a real-valued measurable function $F:\mathbb R^n\to\mathbb R$, define its positive and negative parts by
\begin{align*}
F^+(x):=\max\{F(x),0\}, \qquad F^-(x):=\max\{-F(x),0\}.
\end{align*}
Hence $V$ is bounded below by $m$. Defining
\begin{align*}
m^-:=\max\{-m,0\},
\end{align*}
we have $V^-\le m^-$.
It remains to justify that the positive part of $V$ and the Lebesgue entropy are finite at the endpoints. Fix $i\in\{0,1\}$, and define
\begin{align*}
M_i:=\int_{\mathbb R^n}|x|^2\,d\nu_i(x)<\infty.
\end{align*}
Choose $a>0$ and define the Gaussian probability density $q_a:\mathbb R^n\to(0,\infty)$ by
\begin{align*}
q_a(x):=c_a e^{-a|x|^2}.
\end{align*}
Here $c_a>0$ is the normalising constant satisfying
\begin{align*}
\int_{\mathbb R^n}q_a(x)\,d\mathcal L^n(x)=1.
\end{align*}
By the non-negativity of relative entropy, also called [Gibbs' inequality](/theorems/1629), the relative entropy of $\nu_i$ with respect to the probability measure $q_a\mathcal L^n$ is non-negative in the extended sense. Therefore
\begin{align*}
0\le \int_{\mathbb R^n}\rho_{\nu_i}(x)\log\frac{\rho_{\nu_i}(x)}{q_a(x)}\,d\mathcal L^n(x).
\end{align*}
Thus
\begin{align*}
E_{\mathcal L}(\nu_i)\ge \int_{\mathbb R^n}\rho_{\nu_i}(x)\log q_a(x)\,d\mathcal L^n(x)=\log c_a-aM_i> -\infty.
\end{align*}
The lower bound $V\ge m$ gives $P_V(\nu_i)>-\infty$. Hence the entropy splitting for $\nu_i$ is not an indeterminate expression. Using
\begin{align*}
H(\nu_i\mid\mu)=E_{\mathcal L}(\nu_i)+P_V(\nu_i)+\log Z
\end{align*}
and the hypothesis $H(\nu_i\mid\mu)<\infty$, the lower bound $E_{\mathcal L}(\nu_i)>-\infty$ forces $P_V(\nu_i)<\infty$. Since $V^-$ is bounded, this implies
\begin{align*}
\int_{\mathbb R^n}V^+(x)\,d\nu_i(x)<\infty,
\end{align*}
and hence $P_V(\nu_i)\in\mathbb R$. The same identity then gives $E_{\mathcal L}(\nu_i)\in\mathbb R$.
[/step]