[guided]The goal is to convert the operator commutator into a symbol computation with every $h$-dependent object visible. For Weyl quantization, the semiclassical Weyl symbolic composition theorem says that if $p\in S^\mu(T^*\mathbb{R}^n)$ and $q\in S^\nu(T^*\mathbb{R}^n)$, then $\operatorname{Op}_h^w(p_h)\operatorname{Op}_h^w(q_h)$ is represented, modulo residual semiclassical operators, by $\operatorname{Op}_h^w(p_h\#_w q_h)$. It also gives the stopped Moyal expansion
\begin{align*}
p_h\#_w q_h=\sum_{k=0}^{N-1}\frac{1}{k!}\left(\frac{h}{2i}\right)^k\Lambda_k(p_h,q_h)+h^N e_{N,h},
\end{align*}
where $e_N=(e_{N,h})_{0<h\leq h_0}\in S^{\mu+\nu-N}(T^*\mathbb{R}^n)$ and all symbol seminorm estimates are uniform for $0<h\leq h_0$. The hypotheses are satisfied here with $p=a$, $q=b$, $\mu=m$, $\nu=m'$, and $N=3$, because $a\in S^m(T^*\mathbb{R}^n)$ and $b\in S^{m'}(T^*\mathbb{R}^n)$ are semiclassical symbol families on the same phase space.
Define the bilinear first-order differential operator $\Lambda$ on smooth functions $A,B: T^*\mathbb{R}^n \to \mathbb{C}$ by
\begin{align*}
\Lambda(A,B)(x,\xi) = \sum_{j=1}^n \partial_{\xi_j}A(x,\xi)\,\partial_{x_j}B(x,\xi) - \partial_{x_j}A(x,\xi)\,\partial_{\xi_j}B(x,\xi).
\end{align*}
For $k\in\mathbb{N}$, let $\Lambda_k(A,B)$ be the $k$-fold iterated constant-coefficient symplectic bidifferential operator obtained from $\Lambda$, with $\Lambda_0(A,B):=AB$ and $\Lambda_1(A,B):=\Lambda(A,B)$. Thus the factor $1/k!$ is written separately in the Moyal expansion. With the Poisson bracket convention in the theorem statement,
\begin{align*}
\Lambda_1(a_h,b_h)=\{a_h,b_h\}.
\end{align*}
Applying the stopped expansion to $a_h\#_w b_h$ gives a family $q_3(a,b)=(q_{3,h}(a,b))_{0<h\leq h_0}\in S^{m+m'-3}(T^*\mathbb{R}^n)$ such that
\begin{align*}
a_h \#_w b_h = a_hb_h + \frac{h}{2i}\{a_h,b_h\} + \frac{1}{2}\left(\frac{h}{2i}\right)^2\Lambda_2(a_h,b_h) + h^3 q_{3,h}(a,b).
\end{align*}
The same theorem applies after exchanging the factors, since $b\in S^{m'}(T^*\mathbb{R}^n)$ and $a\in S^m(T^*\mathbb{R}^n)$. Hence there is a family $q_3(b,a)=(q_{3,h}(b,a))_{0<h\leq h_0}\in S^{m+m'-3}(T^*\mathbb{R}^n)$ such that
\begin{align*}
b_h \#_w a_h = b_ha_h + \frac{h}{2i}\{b_h,a_h\} + \frac{1}{2}\left(\frac{h}{2i}\right)^2\Lambda_2(b_h,a_h) + h^3 q_{3,h}(b,a).
\end{align*}
Now subtract the second identity from the first. Scalar multiplication is commutative, so $a_hb_h-b_ha_h=0$. The Poisson bracket is antisymmetric, hence $\{b_h,a_h\}=-\{a_h,b_h\}$, and therefore
\begin{align*}
\frac{h}{2i}\{a_h,b_h\}-\frac{h}{2i}\{b_h,a_h\}=\frac{h}{i}\{a_h,b_h\}.
\end{align*}
The second Moyal coefficient is symmetric under exchanging the two arguments in the Weyl calculus, so $\Lambda_2(a_h,b_h)=\Lambda_2(b_h,a_h)$ and the second-order terms cancel.
Define the family $r_3=(r_{3,h})_{0<h\leq h_0}$ by
\begin{align*}
r_{3,h}=q_{3,h}(a,b)-q_{3,h}(b,a).
\end{align*}
Because $S^{m+m'-3}(T^*\mathbb{R}^n)$ is a vector space and the two remainder families have uniform seminorm estimates, $r_3\in S^{m+m'-3}(T^*\mathbb{R}^n)$. Therefore
\begin{align*}
a_h\#_w b_h-b_h\#_w a_h=\frac{h}{i}\{a_h,b_h\}+h^3r_{3,h}.
\end{align*}
Applying Weyl quantization to this symbol identity gives
\begin{align*}
[\operatorname{Op}_h^w(a_h),\operatorname{Op}_h^w(b_h)] = \frac{h}{i}\operatorname{Op}_h^w(\{a_h,b_h\}) + h^3\operatorname{Op}_h^w(r_{3,h})
\end{align*}
modulo residual semiclassical operators.
For a fixed non-Weyl semiclassical quantization $\operatorname{Op}_h^\kappa$ satisfying the standard symbolic composition formula, the first antisymmetric part of the composition coefficient is still the Poisson bracket. Hence the principal commutator term is again $\frac{h}{i}\operatorname{Op}_h^\kappa(\{a_h,b_h\})$. What changes is the second-order coefficient: without Weyl midpoint symmetry, the degree-two terms in the two products need not agree after exchanging the factors. Therefore the remaining second-order contribution is recorded as $h^2R_h$ with $R_h \in \Psi_h^{m+m'-2}(\mathbb{R}^n)$, modulo residual semiclassical operators, unless an extra symmetry forces that coefficient to cancel.[/guided]