Let $U \subset \mathbb{R}^n$ be open, let $V \Subset U$ be an open subset, and let $m,m' \in \mathbb{R}$. Let $a \in S^m_{1,0}(U \times \mathbb{R}^n)$ and $b \in S^{m'}_{1,0}(U \times \mathbb{R}^n)$ be symbols, viewed either after localization to $V$ or as properly supported representatives. For each $j \in \{1,\dots,n\}$, let $D_{x_j}$ denote the differential operator $-i\partial_{x_j}$. For a multi-index $\alpha = (\alpha_1,\dots,\alpha_n) \in \mathbb{N}_0^n$, write $D_x^\alpha := D_{x_1}^{\alpha_1}\cdots D_{x_n}^{\alpha_n}$, $\partial_\xi^\alpha := \partial_{\xi_1}^{\alpha_1}\cdots \partial_{\xi_n}^{\alpha_n}$, $|\alpha| := \alpha_1+\cdots+\alpha_n$, and $\alpha! := \alpha_1!\cdots\alpha_n!$.
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Let $c \in S^{m+m'}_{1,0}(V \times \mathbb{R}^n)$ be the left-quantized composition symbol, so that on $V$ the left-quantized operator with symbol $c$ represents the composition of the left-quantized operators with symbols $a$ and $b$, modulo smoothing remainders. Assume that $c$ satisfies the left-quantized symbolic composition expansion: for every integer $N \geq 1$,
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\begin{align*}
c - \sum_{|\alpha|<N}\frac{1}{\alpha!}\partial_\xi^\alpha a\,D_x^\alpha b \in S^{m+m'-N}_{1,0}(V \times \mathbb{R}^n).
\end{align*}
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Then
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\begin{align*}
c - ab \in S^{m+m'-1}_{1,0}(V \times \mathbb{R}^n).
\end{align*}
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Consequently, the principal symbol class of $c$ in $S^{m+m'}_{1,0}(V \times \mathbb{R}^n) / S^{m+m'-1}_{1,0}(V \times \mathbb{R}^n)$ is represented by $ab$.
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Moreover,
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\begin{align*}
c - ab - \sum_{j=1}^n \partial_{\xi_j}a\,D_{x_j}b \in S^{m+m'-2}_{1,0}(V \times \mathbb{R}^n).
\end{align*}