[guided]The uniqueness argument is an induction over finite intervals. The point of using interval cardinality is that the recurrence for the value at $(x,y)$ only involves values at $(x,z)$ with $z<y$, and each interval $[x,z]$ is strictly smaller than $[x,y]$.
Let $\nu\in I(P;R)$ be another element satisfying the same diagonal condition and the first recursion:
\begin{align*}
\nu(x,x)=1_R
\end{align*}
for every $x\in P$, and
\begin{align*}
\sum_{x\le z\le y}\nu(x,z)=0_R
\end{align*}
whenever $x<y$. Let
\begin{align*}
C_P=\{(a,b)\in P\times P:a\le b\}
\end{align*}
be the set of comparable ordered pairs in $P$. Define the finite-interval cardinality map $N:C_P\to \mathbb N$ by
\begin{align*}
N(a,b)=|[a,b]|.
\end{align*}
This is finite because $P$ is locally finite.
We prove by induction on $N(x,y)$ that $\nu(x,y)=\mu(x,y)$. If $N(x,y)=1$, then the interval has only one element, so $x=y$. The diagonal condition for $\nu$ and the already-proved diagonal condition for $\mu$ give
\begin{align*}
\nu(x,x)=1_R=\mu(x,x).
\end{align*}
Now suppose $N(x,y)>1$, so $x<y$, and assume the equality is known for all comparable pairs whose interval cardinality is smaller than $N(x,y)$. The recursion for $\nu$ says
\begin{align*}
0_R=\sum_{x\le z\le y}\nu(x,z)=\nu(x,y)+\sum_{x\le z<y}\nu(x,z).
\end{align*}
Rearranging in the additive group of the ring $R$ gives
\begin{align*}
\nu(x,y)=-\sum_{x\le z<y}\nu(x,z).
\end{align*}
The same calculation applies to $\mu$, because $\mu$ satisfies the same recursion:
\begin{align*}
\mu(x,y)=-\sum_{x\le z<y}\mu(x,z).
\end{align*}
For every $z$ with $x\le z<y$, the interval $[x,z]$ is strictly smaller than $[x,y]$: it is contained in $[x,y]$, and it does not contain $y$. Therefore
\begin{align*}
N(x,z)<N(x,y).
\end{align*}
The induction hypothesis applies to each pair $(x,z)$ appearing in the finite sum, so $\nu(x,z)=\mu(x,z)$ for all $z$ with $x\le z<y$. Substituting these equalities into the recurrence formulas gives
\begin{align*}
\nu(x,y)=\mu(x,y).
\end{align*}
This completes the induction, and hence $\nu=\mu$ as elements of $I(P;R)$.[/guided]