[step:Build a $P$-partition from a linear extension and an admissible sequence]
Conversely, let $\pi=(\pi_1,\dots,\pi_n)\in\mathcal L(P,\omega)$. Let $(a_1,\dots,a_n)\in\mathbb N^n$ satisfy
\begin{align*}
1\le a_1\le \cdots \le a_n
\end{align*}
and
\begin{align*}
i\in\operatorname{Des}(\pi)\implies a_i<a_{i+1}.
\end{align*}
Define the map $\sigma_{\pi,a}:P\to\mathbb N$ by
\begin{align*}
\sigma_{\pi,a}(\omega^{-1}(\pi_i))=a_i
\end{align*}
for every $i\in\{1,\dots,n\}$. This is well-defined because $\omega$ is bijective and $\pi$ is a permutation of $\{1,\dots,n\}$.
We verify the $(P,\omega)$-partition inequalities. Let $x,y\in P$ satisfy $x<y$. Since $\pi$ is a linear-extension label word, there exist indices $i<j$ such that $x=\omega^{-1}(\pi_i)$ and $y=\omega^{-1}(\pi_j)$. The weak monotonicity of the sequence gives
\begin{align*}
\sigma_{\pi,a}(x)=a_i\le a_j=\sigma_{\pi,a}(y).
\end{align*}
Now assume also that $\omega(x)>\omega(y)$. Then $\pi_i>\pi_j$. Since the sequence of labels moves from $\pi_i$ to the smaller value $\pi_j$ over the adjacent positions $i,i+1,\dots,j$, there is some $k\in\{i,\dots,j-1\}$ such that $\pi_k>\pi_{k+1}$. Thus $k\in\operatorname{Des}(\pi)$, so $a_k<a_{k+1}$. Combining this strict inequality with the weak inequalities along the sequence gives
\begin{align*}
a_i<a_j.
\end{align*}
Therefore
\begin{align*}
\sigma_{\pi,a}(x)<\sigma_{\pi,a}(y).
\end{align*}
So $\sigma_{\pi,a}$ is a $(P,\omega)$-partition.
[/step]