[guided]Assume that the quantiles are ordered:
\begin{align*}
F^{-1}(p)\le G^{-1}(p)\quad\text{for every }p\in(0,1).
\end{align*}
To prove the pointwise inequality $F\ge G$, we argue by contrapositive. Suppose that the desired pointwise inequality fails. Then there is a point $x_0\in\mathbb R$ such that
\begin{align*}
F(x_0)<G(x_0).
\end{align*}
The purpose of choosing a level strictly between these two values is to force the two quantiles to lie on opposite sides of $x_0$. Since $F(x_0)$ and $G(x_0)$ both belong to $[0,1]$, and the inequality is strict, there exists $p\in(0,1)$ satisfying
\begin{align*}
F(x_0)<p<G(x_0).
\end{align*}
Now we translate the two inequalities involving $F(x_0)$ and $G(x_0)$ into inequalities involving quantiles.
First apply [citetheorem:8346] to the distribution function $G:\mathbb R\to[0,1]$, the level $p\in(0,1)$, and the point $x_0\in\mathbb R$. Its hypotheses are exactly met: $G$ is a distribution function, $p$ lies in $(0,1)$, and $x_0$ is real. Since $p<G(x_0)$, in particular $p\le G(x_0)$, the inverse inequality gives
\begin{align*}
G^{-1}(p)\le x_0.
\end{align*}
Second apply [citetheorem:8346] to the distribution function $F:\mathbb R\to[0,1]$, again with the level $p\in(0,1)$ and the point $x_0\in\mathbb R$. The same hypotheses are satisfied. The equivalence in that theorem says
\begin{align*}
F^{-1}(p)\le x_0\quad\Longleftrightarrow\quad p\le F(x_0).
\end{align*}
But our choice of $p$ gives $F(x_0)<p$, so the right-hand condition is false. Therefore the left-hand condition is false, and hence
\begin{align*}
x_0<F^{-1}(p).
\end{align*}
Putting the two conclusions together yields
\begin{align*}
G^{-1}(p)\le x_0<F^{-1}(p).
\end{align*}
In particular,
\begin{align*}
G^{-1}(p)<F^{-1}(p).
\end{align*}
This contradicts the assumed quantile order at the same level $p$, namely $F^{-1}(p)\le G^{-1}(p)$. The contradiction shows that there is no point $x_0\in\mathbb R$ with $F(x_0)<G(x_0)$. Therefore
\begin{align*}
F(x)\ge G(x)\quad\text{for every }x\in\mathbb R.
\end{align*}[/guided]