[guided]The natural definition is to send the vector produced by a polynomial to the polynomial itself. More precisely, define
\begin{align*}
U_0 : \mathcal{P}_h \to L^2(K,\mu_h)
\end{align*}
on polynomial representatives by
\begin{align*}
U_0(p(A,A^*)h) := p_K,
\end{align*}
where $p_K:K\to\mathbb C$ is the restriction of $p$ to $K$. The only possible problem is that the same vector in $H_h$ might have two different polynomial descriptions. We must prove that this ambiguity disappears in $L^2(K,\mu_h)$.
Assume
\begin{align*}
p(A,A^*)h=q(A,A^*)h.
\end{align*}
Define
\begin{align*}
r:=p-q \in \mathbb{C}[z,\bar z].
\end{align*}
Then
\begin{align*}
r(A,A^*)h=0.
\end{align*}
To show that $p_K$ and $q_K$ define the same element of $L^2(K,\mu_h)$, it is enough to show that $r_K$ has zero $L^2$ norm. By definition of the $L^2(K,\mu_h)$ norm,
\begin{align*}
\|r_K\|_{L^2(K,\mu_h)}^2 = \int_K |r_K(\zeta)|^2\,d\mu_h(\zeta).
\end{align*}
The function $|r_K|^2$ is the restriction to $K$ of the polynomial $\overline r r$ in $z$ and $\bar z$. By the definition of $\mu_h$ through the vector state,
\begin{align*}
\int_K |r_K(\zeta)|^2\,d\mu_h(\zeta)=((\overline r r)(A,A^*)h,h)_H.
\end{align*}
The functional calculus is a $*$-homomorphism, so multiplication of functions becomes multiplication of operators and complex conjugation becomes taking the adjoint. Hence
\begin{align*}
(\overline r r)(A,A^*)=r(A,A^*)^*r(A,A^*).
\end{align*}
Substituting this identity gives
\begin{align*}
\int_K |r_K(\zeta)|^2\,d\mu_h(\zeta)=(r(A,A^*)^*r(A,A^*)h,h)_H.
\end{align*}
Using the defining property of the Hilbert space adjoint,
\begin{align*}
(r(A,A^*)^*r(A,A^*)h,h)_H=\|r(A,A^*)h\|_H^2.
\end{align*}
Since $r(A,A^*)h=0$, we obtain
\begin{align*}
\|r_K\|_{L^2(K,\mu_h)}^2=0.
\end{align*}
Therefore $p_K=q_K$ in $L^2(K,\mu_h)$, so $U_0$ is well-defined.
The same argument with $q=0$ shows that $U_0$ preserves norms:
\begin{align*}
\|U_0(p(A,A^*)h)\|_{L^2(K,\mu_h)}^2=\|p(A,A^*)h\|_H^2.
\end{align*}
Thus $U_0$ is an isometry from the polynomial-vector subspace into $L^2(K,\mu_h)$.[/guided]